Three in one: engineering MOF channels coordinated water arrays for regulated separation of alkanes and alkenes.

Purifying alkenes (mainly ethylene and propylene) by removing their corresponding alkanes is crucial yet challenging in the chemical industry. Selective physisorption shows promise for effective separation but demands precise pore dimensions and/or pore chemistry of adsorbents. We report an yttrium-based metal-organic framework, Y(TCHB)(OH)·2HO (HIAM-317, TCHB = 3,3',5,5'-tetrakis(4-carboxyphenyl)-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl), that can separate ethylene/ethane and propylene/propane mechanisms regulated by coordinated water arrays.

A Sodium Germanosilicide with Unusual Network Topology.

The germanosilicide NaGeSi (0.4 ≤ ≤ 1.1, 4.

A redox active rod coordination polymer from tetrakis(4-carboxylic acid biphenyl)tetrathiafulvalene.

An enlarged version of the ubiquitous tetrathiafulvalene-tetrabenzoic acid is described, with 4,4'-biphenyl moieties as spacers between the coordination moieties and the electroactive core. The obtained rectangular ligand has a 14 × 22 Å size and is combined with Zn(II) under solvothermal conditions to yield a coordination polymer endowed with large cavities of . 15 × 11 Å/10 × 10 Å.

An Octacarboxylate-Linked Sodium Metal-Organic Framework with High Porosity.

Alkali metal-based metal-organic frameworks (MOFs) with permanent porosity are scarce because of their high tendency to coordinate with solvents such as water. However, these MOFs are lightweight and bear gravimetric benefits for gas adsorption related applications. In this study, we present the successful construction of a microporous MOF, designated as HIAM-111, built solely on sodium ions by using an octacarboxylate linker.