Contribution to the Analysis of the 3A2 <-- &Xtilde;1A1 "Wulf" Transition of Ozone by High-Resolution Fourier Transform Spectrometry.

The analysis of the rotational structure of the high-resolution Fourier transform 0(0)0 absorption spectrum of the 3A2 <-- &Xtilde;1A1 band system of the "Wulf" transition of the isotopomer 16O3 of ozone is reported for the first time. With a near pure case (b) coupling model for the upper triplet state, we have assigned a significant portion of the spectrum, mainly the F1 (J = N + 1) and F2 (J = N) spin components, primarily in the lower frequency region of the band. The lines corresponding to the F3 (J = N - 1) component are weak at lower frequencies and heavily congested in the central and higher frequency regions of the spectrum.