Porous crystalline dipeptides absorb, reversibly from the gas phase, a series of volatile fluorinated ethers in use as anesthetics. Their vapor pressure was considerably reduced, with favorable guest capture and release. Variable channel sizes were customized for selective sorption and pressure thresholds were observed in the narrowest pores.
View Article and Find Full Text PDFCombinations of two enantiomerically pure organic tectons 1 and 3 with either Zn(ii) or Cu(ii) cations lead to the formation of four homochiral 3D networks among which two, 1-Cu and 3-Cu, are robust porous crystals displaying homochiral cavities and permanent microporosity. 3-Cu porous crystals capture 66% and 20% of l- and d-tryptophan, respectively, after 30 min of adsorption.
View Article and Find Full Text PDFInt J Clin Oncol
June 2013
Background: Set-up errors represent a source of uncertainty in head and neck (H&N) cancer radiotherapy. The present study evaluated set-up accuracy with the use of cone-beam computed tomography (CBCT) in order to establish the proper clinical target volume (CTV) to planning target volume (PTV) margins to be adopted.
Methods: Local set-up accuracy was analysed for 44 H&N cancer patients since the implementation of CBCT.
Purpose: To quantify the impact of radiotherapy technique on cosmetic outcome and on 5-year local control rate of early breast cancer treated with conservative surgery and adjuvant radiation.
Methods And Materials: A total of 1,176 patients irradiated to the breast in 1997 were entered by eight centers into a prospective, observational study. Surgical procedure was quadrantectomy in 97% of patients, with axillary dissection performed in 96%; pT-stage was T1 in 81% and T2 in 19% of cases; pN-stage was N0 in 71%, N + (1-3) in 21%, and N + (>3) in 8% of cases.