Spin polarization through axially chiral linkers: Length dependence and correlation with the dissymmetry factor.

The chiral-induced spin selectivity (CISS) effect relates to the spin-selective electron transport through chiral molecules; therefore, the chiral molecules act as spin filters. In past studies, correlation was found between the magnitude of the spin filtering and the intensity of the circular dichroism (CD) spectrum (the first Compton peak) of the molecules. Since the intensity of the CD peak relates to both the magnitude of the electric and magnetic dipole transitions, it was not clear which of these properties correlate with the CISS effect.

Novel Series of Diaminoanthraquinone-Based π-Extendable Building Blocks with Tunable Optoelectronic Properties.

We have achieved the first series of -based building blocks, viz., s ( = 1-4), and unraveled a rational design of their π-extension. Sequentially increasing numbers () of the exocyclic π-linkers showed (a) a systematic bathochromic shift in both absorption and emission spectra, (b) selective stabilization of the lowest-unoccupied molecular orbital (LUMO), and (c) unselective changes in the S/S states.

Impact of pharmacist medication review for paediatric patients: an observational study.

Background: Paediatric patients are at high risk of medication errors and adverse drug events due to complex medical care.

Objective: To assess the impact of pharmacist medication review for paediatric patients.

Setting: A single-centre prospective observational study was performed over 33 months, from February 2018 to October 2020 in a French Hospital.

The Largest Germline Heterozygous Deletion Encompassing Potocki-Shaffer and WAGR Syndromes Loci to Date: A Case Report.

Potocki-Schaffer syndrome includes multiple exostoses, parietal foramina, and variable developmental delay/intellectual disability. It is associated with a heterozygous deletion of the 11p12p11.2 region.