Multicomponent self-assembly has been explored to create novel metamaterials from nanoparticles of different sizes and compositions, but the assembly of nanoparticles with complementary shapes remains rare. Recent binary assemblies were mediated by DNA base pairing or induced by solvent evaporation. Here, we introduce depletion-induced self-assembly (DISA) as a novel approach to constructing tunable binary lattices.
View Article and Find Full Text PDFDepletion-induced self-assembly is routinely used to separate plasmonic nanoparticles (NPs) of different shapes, but less often for its ability to create supercrystals (SCs) in suspension. Therefore, these plasmonic assemblies have not yet reached a high level of maturity and their in-depth characterization by a combination of in situ techniques is still very much needed. In this work, gold triangles (AuNTs) and silver nanorods (AgNRs) are assembled by depletion-induced self-assembly.
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