Efficient second harmonic generation and broad-band photoluminescence from deeply subwavelength and nontoxic nanoparticles is essential for nanophotonic applications. Here, we explore nonlinear optical response from mesoporous Si/SiO, SiO, and Si nanoparticles, considering various fabrication and treatment procedures. We show that thermal annealing (including femtosecond laser treatment) of mesoporous Si/SiO nanoparticles provides the transformation of Si phase from amorphous to crystalline, enhancing the second harmonic and nonlinear photoluminescent response.
View Article and Find Full Text PDFNew organic nanostructures were synthesized by introducing 2-methylbenzimidazole (MBI) molecules from a melt, gas phase, or alcoholic solution into nanosized voids of borate porous glasses (PG), nanotubes of chrysotile asbestos (ChA), and mesoporous silica (MS). The incorporation of MBI into borate glasses with different pore sizes is accompanied by the appearance of several phases formed by nanocrystallites which have a MBI crystal structure, but somewhat differ in lattice parameters. The size of some crystallites significantly exceeds the size of nanopores, which indicates the presence of long-scale correlations of the crystal structure.
View Article and Find Full Text PDFApplication Progress and Insights of Nanoporous Materials is an open Special Issue in , which aims to publish original research and review papers concerning fundamental and applied aspects of nanoporous materials of various composition and morphology, investigation of their properties and underlying mechanisms for fabrication of porous media with the desired characteristics [...
View Article and Find Full Text PDF"Applications of Porous Nanotubes" is an open Special Issue of , which aims to publish original contributions and review papers on new fundamental and applied aspects of porous nanomaterials, and to investigate their properties and underlying mechanisms for development of various porous media with a desired functionality [...
View Article and Find Full Text PDFCarbon dots (CDs) with an emission in the near infrared spectral region are attractive due to their promising applications in bio-related areas, while their fabrication still remains a challenging task. Herein, we developed a template-assisted method using porous silica microspheres for the formation of CDs with optical transitions in the near infrared. Two organic dyes, Rhodamine 6G and IR1061 with emission in the yellow and near infrared spectral regions, respectively, were used as precursors for CDs.
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