Visible-light-driven photoelectrochemical sensor based on conjugated microporous polymer-grafted graphene for -aminophenol detection.

The pollutant -aminophenol (-AP) presents considerable risk to environmental safety, and its detection is therefore critical. Although various optical and electrochemical methods have been proposed for the detection of -AP, there are a limited number of detection methods based on photoelectrochemical (PEC) sensors. In this study, a sensitive visible-light-driven PEC sensor was developed for -AP detection in water.

A simple photoelectrochemical aptasensor based on MoS/rGO for aflatoxin B1 detection in grain crops.

Designing a simple and sensitive photoelectrochemical (PEC) sensor is crucial to addressing the limitations of routine analytical methods. The sensitivity of the PEC sensor, however, relies on the photoelectric material used. In this manuscript, composites of MoS/rGO (MG) with a large area and layered structure are prepared by simple steps.

A Tröger's base-linked aluminium phthalocyanine polymer for discriminative electrochemical sensing of the antibiotic isoniazid.

Isoniazid is a first-line drug used to treat tuberculosis. However, its excessive use can lead to serious adverse effects. Thus, strict monitoring of the isoniazid levels in medications and human systems is required.

Conductive phthalocyanine-based porous organic polymer as sensing platform for rapid determination of vanillin.

Vanillin (Van) is widely utilized in processed foods and medicines for its appealing scent and multiple therapeutic benefits. However, its overconsumption poses a risk to public health, making its quantification essential for ensuring food and medicine safety and quality. This study introduces a stable and conductive phthalocyanine-based porous organic polymer (NiPc-CC POP), synthesized through a straightforward electrophilic substitution of nickel tetra-amine phthalocyanine (NiTAPc) with cyanuric chloride (CC).

Synergistic effect of photoelectrochemical aptasensor based on staggered gap ZnO/BiFeO heterojunction coupled with cDNA-CdS sensitizer enabling ultrasensitive assay of kanamycin.

Using staggered-gap ZnO/BiFeO heterojunction as photoactive materials and cDNA-CdS as the sensitizer for sensitive Kanamycin (KAN) detection, we have created a unique signal-off biosensing platform. The ZnO/BiFeO heterojunction provides active sites for aptamer loading and enhances photocurrent responsiveness. Rapid interfacial charge transfer and the separation efficiency of photo-generated carriers are enhanced by sensitization of the ternary heterojunction ZnO/BiFeO/CdS.

A Sensitive Photoelectrochemical Sensor for Levodopa Detection Using Benzothiadiazole-Based Conjugated Microporous Polymer-Coated Graphene Heterostructures.

Since the 1960s, levodopa (LDA) has been the standard drug for treating of Parkinson's disease. In this study, a novel benzothiadiazole-based conjugated microporous polymer-coated graphene heterostructure (CMP-rGO) was synthesized and used to construct a sensitive photoelectrochemical (PEC) sensor capable of detecting LDA. Under optimal experimental conditions, the intensity of the photocurrent produced by the sensor was linear from 0.

Photoelectrochemical detection for 3,3',4,4'-tetrachlorobiphenyl in fish based on synergistic effects by Schottky junction and sensitization.

In this study, a novel signal amplification strategy on photoelectrochemical (PEC) aptasensor was designed for high-sensitivity and -selectivity detection of 3,3',4,4'-tetrachlorobiphenyl (PCB77) on the basis of Schottky junction and sensitization. First, the Schottky barrier not only provided an electron-transfer irreversible passage from CuO to Au Nanoparticles (NPs) but also generated excellent local surface plasmon resonance between CuO and Au NPs, thus improving the efficiency of charge separation and light absorption. Second, to further improve the response of the PEC aptasensor under the action of the sensitization, the complementary-DNA-functionalized CdS quantum dots were introduced onto the surface of CuO/Au NPs via hybridization of the target aptamer.

Novel porous iron phthalocyanine based metal-organic framework electrochemical sensor for sensitive vanillin detection.

Vanillin is widely used as a flavor enhancer and is known to have numerous other interesting properties, including antidepressant, anticancer, anti-inflammatory, and antioxidant effects. However, as excess vanillin consumption can affect liver and kidney function, simple and rapid detection methods for vanillin are required. Herein, a novel electrochemical sensor for the sensitive determination of vanillin was fabricated using an iron phthalocyanine (FePc)-based metal-organic framework (MOF).

Au Quantum Dot/Nickel Tetraminophthalocyanaine-Graphene Oxide-Based Photoelectrochemical Microsensor for Ultrasensitive Epinephrine Detection.

Owing to the importance of epinephrine as a neurotransmitter and hormone, sensitive methods are required for its detection. We have developed a sensitive photoelectrochemical (PEC) microsensor based on gold quantum dots (Au QDs) decorated on a nickel tetraminophthalocyanine-graphene oxide (NiTAPc-Gr) composite. NiTAPc was covalently attached to the surface of graphene oxide to prepare NiTAPc-Gr, which exhibits remarkable stability and PEC performance.