Cucurbit[6]uril-Derived Nitrogen-Doped Hierarchical Porous Carbon Confined in Graphene Network for Potassium-Ion Hybrid Capacitors.

Potassium-ion hybrid capacitors (PIHCs) have attracted tremendous attention because their energy density is comparable to that of lithium-ion batteries, whose power density and cyclability are similar to those of supercapacitors. Herein, a pomegranate-like graphene-confined cucurbit[6]uril-derived nitrogen-doped carbon (CBC@G) with ultra-high nitrogen-doping level (15.5 at%) and unique supermesopore-macropores interconnected graphene network is synthesized.

Cucurbit[6]uril-Derived Sub-4 nm Pores-Dominated Hierarchical Porous Carbon for Supercapacitors: Operating Voltage Expansion and Pore Size Matching.

The intrinsic properties of carbon-based material and the voltage window of electrolyte are the two key barriers to restrict the energy density of carbon-based supercapacitors (SCs). Herein, a cucurbit[6]uril-derived nitrogen-doped hierarchical porous carbon (CBCx) with unique pore structure characteristics is synthesized and successfully applied to construct SCs based on different electrolyte systems. Owing to narrow pore size distribution (0.

Homologous Hierarchical Porous Hollow Carbon Spheres Anode and Bowls Cathode Enabling High-Energy Sodium-Ion Hybrid Capacitors.

It is a highly expected avenue to construct dual-carbon sodium-ion hybrid capacitors (SIHCs) using hierarchical porous carbon with interconnected pores, high accessible surface area, and disordered carbon frameworks for ameliorating the sluggish kinetics of SIHCs. In this work, a novel dual-carbon SIHCs system with homologous enhanced kinetics hierarchical porous hollow carbon spheres (HPCS) and hierarchical porous hollow carbon bowls (HPCB) as the anode and cathode is constructed for the first time. In a Na half-cell configuration, the HPCS anode synthesized through a facile one-pot in-situ template route demonstrates a superior reversible capacity as well as outstanding rate capability and cycleability, and the HPCB cathode fabricated by chemical activation of HPCS exhibits excellent capacitive behaviors.