Electrochemical Deposition of Silver Nanoparticle Assemblies on Carbon Ultramicroelectrode Arrays.

Silver nanoparticle (AgNP) assemblies combined with electrode surfaces have a myriad of applications in electrochemical energy storage and conversion devices, (bio)sensor development, and electrocatalysis. Among various nanoparticle synthesis methods, electrochemical deposition is advantageous due to its ability to control experimental parameters, enabling the formation of low-nanoscale (<10 nm) particles with narrow size distributions. Herein, we report the electrodeposition of AgNPs on a unique electrode platform based on carbon ultramicroelectrode arrays (CUAs), exploring several experimental variables including potential, time, and silver ion concentration.

Electrochemical deposition of gold nanoparticles on carbon ultramicroelectrode arrays.

Electrode surfaces functionalized with gold nanoparticles (AuNP) are widely used in electroanalysis, electrocatalysis, and electrochemical biosensing due to their increased surface area and conductivity. Electrochemical deposition of AuNPs offers advantages over chemical synthesis, including better control over AuNP size, dispersion, and morphology. This study examines the electrodeposition of AuNPs on carbon ultramicroelectrode arrays (CUAs) focusing on electrodeposition parameters, such as deposition potential, deposition time, and gold ion concentration.

Advances in electrochemical biosensor design for the detection of the stress biomarker cortisol.

The monitoring of stress levels in humans has become increasingly relevant, given the recent incline of stress-related mental health disorders, lifestyle impacts, and chronic physiological diseases. Long-term exposure to stress can induce anxiety and depression, heart disease, and risky behaviors, such as drug and alcohol abuse. Biomarker molecules can be quantified in biological fluids to study human stress.