Corrosion Behavior of Coated Low Carbon Steel in a Simulated PEMFC Environment.

Here, potential metallic bipolar plate (BP) materials were manufactured by laser coating NiCr-based alloys with different Ti additions on low carbon steel substrates. The titanium content within the coating varied between 1.5 and 12.

Electrochemical Evaluation of Protective Coatings with Ti Additions on Mild Steel Substrate with Potential Application for PEM Fuel Cells.

In this work, the corrosion behavior of NiCr(Ti) protective coatings deposited on mild steel substrates through laser cladding technology is studied as an alternative new material for metallic bipolar plates used in PEMFC applications. For electrochemical testing, a solution consisting of 0.5 M HSO + 2 ppm F at room temperature is used as an electrolyte.

Antimicrobial Activity of Cellulose Based Materials.

Biomaterials available for a wide range of applications are generally polysaccharides. They may have inherent antimicrobial activity in the case of chitosan. However, in order to have specific functionalities, bioactive compounds must be immobilized or incorporated into the polymer matrix, as in the case of cellulose.

Antimicrobial Activities of Chitosan Derivatives.

Considering the challenge created by the development of bacterial and fungal strains resistant to multiple therapeutic variants, new molecules and materials with specific properties against these microorganisms can be synthesized, like those synthesized from biopolymers such as chitosan with improved antimicrobial activities. Antimicrobial activities of seven obtained materials were tested on four reference strains belonging to American Type Culture Collection. The best antimicrobial activity was obtained by functionalization by impregnation of chitosan with quaternary ammonium salts, followed by that obtained by functionalization of chitosan with phosphonium.

Factors Influencing the Antibacterial Activity of Chitosan and Chitosan Modified by Functionalization.

The biomedical and therapeutic importance of chitosan and chitosan derivatives is the subject of interdisciplinary research. In this analysis, we intended to consolidate some of the recent discoveries regarding the potential of chitosan and its derivatives to be used for biomedical and other purposes. Why chitosan? Because chitosan is a natural biopolymer that can be obtained from one of the most abundant polysaccharides in nature, which is chitin.

Kinetics and Thermodynamics Studies for Cadmium (II) Adsorption onto Functionalized Chitosan with Hexa-Decyl-Trimethyl-Ammonium Chloride.

A new adsorbent material was obtained by functionalization of chitosan with hexa-decyl-trimethyl-ammonium chloride and tested as an adsorbent for Cd(II) ions. Functionalization is due to the desire to improve the adsorbent properties of the biopolymer used for removal of metallic ions. Obtained material was characterized by FTIR (Fourier Transform InfraRed spectroscopy), SEM (Scanning Electron Microscopy) and EDX (Energy dispersive X-ray Spectroscopy).

New Generation of Antibacterial Products Based on Colloidal Silver.

The main objective of the present paper is the green synthesis of colloidal silver by ultrasonication starting from silver nitrate and using soluble starch as the reducing agent. Soluble starch has been used during synthesis because it is a cheap and environmentally friendly reactive. Silver colloid has been characterized by physicochemical methods: UV-VIS spectroscopy, Scanning Electron Microscopy and Energy Dispersive X-Ray spectroscopy.

Modified Chitosan for Silver Recovery-Kinetics, Thermodynamic, and Equilibrium Studies.

：The aim of this study is to investigate the silver recovery from aqueous solutions. There are a variety of recovery methods, such as hydrometallurgical, bio-metallurgical, cementation, reduction, electrocoagulation, electrodialysis, ion exchange, etc. Adsorption represents a convenient, environment friendly procedure, that can be used to recover silver from aqueous solutions.

Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid.

The main purpose of this paper was to obtain a material with efficient adsorbing properties and selectivity, to recover the gold (III) from residual diluted solutions resulted from the electroplating process. In this regard, a material was obtained by physico-chemical functionalization of a chemically inert support with functional groups of nitrogen and carboxyl. As a source of functional groups glutamic acid was used, and Amberlite XAD7 type acrylic resin was used as solid support.

Rare Earth Elements Removal from Water Using Natural Polymers.

Adsorption of rare earth metals, Eu (III) and Nd (III) was investigated on a new environmental friendly material, thiourea functionalized cellulose. Before usage, the synthesized material was characterized by Fourrier Transform Infrared spectroscopy and energy dispersive X-ray analysis. The influence of adsorption parameters (adsorbent dosage, time, temperature and initial metal concentration) on adsorption capacity was investigated.

Optimizing the lanthanum adsorption process onto chemically modified biomaterials using factorial and response surface design.

The rare metals' potential to pollute air, water, soil, and especially groundwater has received lot of attention recently. One of the most common rare earth group elements, lanthanum, is used in many industrial branches, and due to its toxicity, it needs to be eliminated from all residual aqueous solutions. The goal of this study was to evaluate the control of the adsorption process for lanthanum removal from aqueous solutions, using cellulose, a known biomaterial with high adsorbent properties, cheap, and environment friendly.

Behaviour of silica and florisil as solid supports in the removal process of as(v) from aqueous solutions.

In this study two solid supports, silica and florisil, were impregnated with crown ether (dibenzo-18-crown-6) and Fe(III) ions and their efficiency was compared in the adsorption process of As(V) from aqueous solutions. The solid supports were impregnated with crown ether due to their ability to build complexes with positives ions. Fe(III) was used because of As(V) affinity for it.

Studies regarding as(V) adsorption from underground water by Fe-XAD8-DEHPA impregnated resin. equilibrium sorption and fixed-bed column tests.

The characteristics of arsenic adsorption onto Fe-XAD8-DEHPA resin were studied on the laboratory scale using aqueous solutions and natural underground waters. Amberlite XAD8 resin was impregnated with di(2-ethylhexyl) phosphoric acid (DEHPA) via the dry method of impregnation. Fe(III) ions were loaded onto the impregnated resin by exploiting the high affinity of arsenic towards iron.