Effects of CNTs on thermal transitions, thermal diffusivity and electrical conductivity in nanocomposites: comparison between an amorphous and a semicrystalline polymer matrix.

Two series of polymer nanocomposites (PNCs) based on amorphous styrene-butadiene rubber (SBR) and semicrystalline linear low-density polyethylene (PE) matrices were filled with 2-15 wt% carbon nanotubes (CNT) and were studied by employing calorimetry, dielectric spectroscopy and laser flash analysis. The electrical conductivity, σ, increased with CNT loading and similar values were exhibited for the two matrices, uniquely depending on the concentration of the CNTs, suggesting practically no effects of the crystalline fraction (CF) on σ. For both types of matrix, a fraction of the polymer was found to be immobilized (rigid amorphous fraction, RAF).