Publications by authors named "Constantin Daniel Negut"

This work presents an extensive, comparative study of the gamma and electron radiation effects on the behaviour of femtosecond laser-inscribed fibre Bragg gratings (FBGs) using the point-by-point and plane-by-plane inscription methods. The FBGs were inscribed in standard telecommunication single mode silica fibre (SMF28) and exposed to a total accumulated radiation dose of 15 kGy for both gamma and electron radiation. The gratings' spectra were measured and analysed before and after the exposure to radiation, with complementary material characterisation using Fourier transform infrared (FTIR) spectroscopy.

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In this work, we present a new setup for real-time investigations of optical fibers and optical fiber sensors while being subjected to gamma-rays. The investigation of the radiation effects on novel or well-assessed sensing devices has attracted a lot of interest, however, the facilities required to do this (when available) are barely accessible to the device to be characterized. In order to reduce the limitations of these types of experiments and ensure a highly controlled environment, we implemented a configuration that permits the on-line testing of optical components inside a Co-60 gamma chamber research irradiator.

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In the present work, we attempted to develop new metal coordination complexes of the natural flavonoid 5-hydroxyflavone with Sm(III), Eu(III), Gd(III), Tb(III). The resultant hydroxo complexes have been characterized by a variety of spectroscopic techniques, including fluorescence, FT-IR, UV-Vis, EPR and mass spectral studies. The general chemical formula of the complexes is [Ln(CH₉O₃)₃(OH)₂(H₂O)]·H₂O, where Ln is the lanthanide cation and x = 0 for Sm(III), x = 1 for Eu(III), Gd(III), Tb(III) and = 0 for Sm(III), Gd(III), Tb(III), = 1 for Eu(III), respectively.

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