Growth of millimeter-sized 2D metal iodide crystals induced by ion-specific preference at water-air interfaces.

Conventional liquid-phase methods lack precise control in synthesizing and processing materials with macroscopic sizes and atomic thicknesses. Water interfaces are ubiquitous and unique in catalyzing many chemical reactions. However, investigations on two-dimensional (2D) materials related to water interfaces remain limited.

Transient Photoinduced Pb Disproportionation for Exciton Self-Trapping and Broadband Emission in Low-Dimensional Lead Halide Perovskites.

Low-dimensional lead halide perovskites with broadband emission hold great promise for single-component white-light-emitting (WLE) devices. The origin of their broadband emission has been commonly attributed to self-trapped excitons (STEs) composed of localized electronic polarization with a distorted lattice. Unfortunately, the exact electronic and structural nature of the STE species in these WLE materials remains elusive, hindering the rational design of high-efficiency WLE materials.

Excessive Iodine Enabled Ultrathin Inorganic Perovskite Growth at the Liquid-Air Interface.

The liquid-air interface offers a platform for the in-plane growth of free-standing materials. However, it is rarely used for inorganic perovskites and ultrathin non-layered perovskites. Herein the liquid-air interfacial synthesis of inorganic perovskite nanosheets (Cs Bi I , Cs Sb I ) is achieved simply by drop-casting the precursor solution with only the addition of iodine.

Characteristics of hydrochemistry and nitrogen behavior under long-term managed aquifer recharge with reclaimed water: A case study in north China.

Due to the quality difference between reclaimed water and natural groundwater, managed aquifer recharge (MAR) with reclaimed water may pose environmental risks. A river infiltration of reclaimed water for groundwater recharge in north China has been in operation for over 10 years. To investigate the actual impact on native groundwater under long-term MAR, 10-year monitoring data of recharge water and groundwater were analyzed.