Enhancing Mechanical Durability and Long-Term Stability in Organic Solar Cells via Flexible Linker-Sequential Block Copolymerized Donors.

Multi-component copolymerized donors (MCDs) hold great promise for improving both the efficiency and mechanical robustness of flexible organic solar cells (f-OSCs) owing to their facile molecular tunability and advantageous one-pot copolymerization. However, despite the excellent crystallinity imparted by their highly conjugated polymer backbone, MCDs often struggle to retain photovoltaic performance under large external deformations, limiting their applicability in wearable devices. Herein, we developed a novel series of flexible linker-sequential block MCDs (Fs-MCDs), specifically PM6-Cl-b-D18-Cl-BTB, PM6-Cl-b-D18-Cl-BTH, and PM6-Cl-b-D18-Cl-BTD, by precisely incorporating flexible functional groups into the conjugated polymer skeleton.

Multi-component Copolymerized Donors enable Frozen Nano-morphology and Superior Ductility for Efficient Binary Organic Solar Cells.

Multi-component copolymerized donors (MCDs) have gained significant interest and have been rapidly developed in flexible organic solar cells (f-OSCs) in recent years. However, ensuring the power conversion efficiency (PCE) of f-OSCs while retaining ideal mechanical properties remains an enormous challenge. The fracture strain (FS) value of typical high-efficiency blend films is generally less than 8 %, which is far from the application standards of wearable photovoltaic devices.