Using oxidizing compounds to handle the recycling of discarded lithium batteries has advanced significantly in recent years. One of the most prominent methods is the sintered electrode powder treatment using pre-used additives, with an aqueous solution of the oxidizing agent fueling highly selective lithium extraction and transition metals retention in the refractory material. Herein, phosphoric acid (HPO) was used as the exchanger and hydrogen ions provider, the oxidant (KSO) activity was driven by heating, the raw material structure was deformed and adjusted by the oxidizing drive, and lithium was exhausted, while manganese was converted into manganese(III) phosphate hydrate and manganese dioxide insoluble material.
View Article and Find Full Text PDFCurrently, the surface structure modification of photocatalysts is one of the effective means of enhancing their photocatalytic efficiency. Therefore, it is critically important to gain a deeper understanding of how the surface of α-FeO photocatalysts influences catalytic activity at the nanoscale. In this work, α-FeO catalysts were prepared using the solvothermal method, and four distinct morphologies were investigated: hexagonal bipyramid (THB), cube (CB), hexagonal plate (HS), and spherical (RC).
View Article and Find Full Text PDFWe propose a novel strategy for the synthesis of pyruvic acid from bio-lactic acid in air. Polyvinylpyrrolidone can regulate the growth of the crystal face and formation of oxygen vacancies, in which a synergy of the facet and vacancies boosted the oxidative dehydrogenation of lactic acid into pyruvic acid.
View Article and Find Full Text PDFIn this work, a polyethyleneimine-modified chitosan/Ce-UIO-66 composite hydrogel (PEI-CS/Ce-UIO-66) was prepared using the ex-situ blend method. The synthesized composite hydrogel was characterized by SEM, EDS, XRD, FTIR, BET, XPS, and TG techniques, while the zeta potential was recorded for sample analysis. The adsorbent performance was studied by conducting adsorption experiments using methyl orange (MO), which showed that PEI-CS/Ce-UIO-66 exhibited excellent MO adsorption properties (900.
View Article and Find Full Text PDFAs a biomass resource, corncob is a kind of agricultural by-product with wide sources and low cost. Because its composition contains a large number of functional polymers such as cellulose, chitosan, and semi chitosan, corncob can be chemically modified to prepare a variety of adsorption materials. In this study, a magnetic gel material (PEI-CC@FeO) consisting of corncob modified by glutaraldehyde-crosslinked polyethyleneimine (PEI) was successfully prepared and applied to the adsorption of heavy metal ions in aqueous solutions.
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