Large, Tunable Liquid Crystal Pretilt Achieved by Enhanced Out-of-Plane Reorientation of Azodye Thin Films.

In-plane, or azimuthal, photo-reorientation of azodye films using polarized exposure makes them promising alignment layers for a host of liquid crystal (LC) applications beyond displays including beam steering, q-plates, liquid crystal elastomer origami, and control of active matter. Out-of-plane, or polar, reorientation of azodye films, which dictates the liquid crystal pretilt, has received far less attention. Spatial control over the full polar and azimuthal orientation enables the generation of complex patterns that have broad interests and applications.