Co-extrusion of both half-cells in tubular PEM water electrolyzers can lower the costs for hydrogen production, since the number of components is reduced and the production process is simplified. However, after co-extrusion of the inner half-cell and the ion exchange membrane, the membrane is in its fluoride sulfonyl form and must be hydrolyzed to achieve the proton conductive sulfonic acid to be ready for use. Common practice is the hydrolysis using concentrated alkaline solutions, which causes a corrosion of the laminated anode electrode.
View Article and Find Full Text PDFElectro-Fenton (EF) represents an eco-friendly and cost-effective advanced oxidation process that can remove highly persistent and hazardous pharmaceuticals, e.g., contrast media agents, from water bodies.
View Article and Find Full Text PDFMembranes play a crucial role in efficiency and longevity of flow batteries. Vanadium flow batteries suffer self-discharge and capacity fading due to crossover of electrolyte components through the membrane from one battery half-cell to the other. We consider the impact of vanadium species crossing ion exchange membranes on state of charge of the battery and we present a simple method to determine crossoverll open circuit potential measurements.
View Article and Find Full Text PDFWe provide a direct comparison of two distinct methods of Ti felt surface treatment and Pt/Ir electrocatalyst deposition for the positive electrode of regenerative fuel cells and vanadium-air redox flow batteries. Each method is well documented in the literature, and this paper provides a direct comparison under identical experimental conditions of electrochemical measurements and in identical units. In the first method, based on classical engineering, the bimetallic catalyst is deposited by dip-coating in a precursor solution of the salts followed by their thermal decomposition.
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