Precise measurements of the total concentration of atmospheric CO2 and 13CO2/12CO2 isotopic ratio using a lead-salt laser diode spectrometer.

We have developed a tunable diode laser spectrometer, called SIMCO (spectrometer for isotopic measurements of CO(2)), for determining the concentrations of (12)CO(2) and (13)CO(2) in atmospheric air, from which the total concentration of CO(2) and the isotopic composition (expressed in delta units) delta(13)CO(2) are calculated. The two concentrations are measured using a pair of lines around 2290.1 cm(-1), by fitting a line profile model, taking into account the confinement narrowing effect to achieve a better accuracy.

SPIRALE: a multispecies in situ balloonborne instrument with six tunable diode laser spectrometers.

The balloonborne SPIRALE (a French acronym for infrared absorption spectroscopy by tunable diode lasers) instrument has been developed for in situ measurements of several tracer and chemically active species in the stratosphere. Laser absorption takes place in an open Herriott multipass cell located under the balloon gondola, with six lead salt diode lasers as light sources. One mirror is located at the extremity of a deployable mast 3.

Concentration measurements of ozone in the 1200-300ppbv range: an intercomparison between the BNM ultraviolet standard and infrared methods.

Simultaneous ultraviolet (UV) and infrared (IR) measurements of ozone concentration in air in the 1200-300 ppbv range have been performed using the ultraviolet absorption in the Hartley band at 0.2537 microm and the infrared absorption of a doublet at 9.507 microm in the nu(3) vibration-rotation band.

Retrieval of CO from nadir remote-sensing measurements in the infrared by use of four different inversion algorithms.

Four inversion schemes based on various retrieval approaches (digital gas correlation, nonlinear least squares, global fit adjustment, and neural networks) developed to retrieve CO from nadir radiances measured by such downward-looking satelliteborne instruments as the Measurement of Pollution in the Troposphere (MOPITT), the Tropospheric Emission Spectrometer (TES), and the Infrared Atmospheric Sounding Interferometer (IASI) instruments were compared both for simulated cases and for atmospheric spectra recorded by the Interferometric Monitor for Greenhouse Gases (IMG). The sensitivity of the retrieved CO total column amount to properties that may affect the inversion accuracy (noise, ancillary temperature profile, and water-vapor content) was investigated. The CO column amounts for the simulated radiance spectra agreed within 4%, whereas larger discrepancies were obtained when atmospheric spectra recorded by the IMG instrument were analyzed.

Balloonborne calibrated spectroradiometer for atmospheric nadir sounding.

Laboratoire de Physique Moléculaire et Applications (LPMA)/Infrared Atmospheric Sounding interferometer (IASI) balloon is a calibrated infrared Fourier transform spectrometer that is used to measure the Earth's atmospheric emission (650-3000 cm(-1)). Operating under a stratospheric balloon, this spectroradiometer provides radiometrically calibrated spectra with an apodized spectral resolution of 0.1 cm(-1), which can be used to retrieve the concentration of atmospheric trace gases such as H2O, CO2, CO, O3, N2O, and CH4.

Diode-Laser Spectroscopy: Line Profiles of H(2)O in the Region of 1.39 &mgr;m.

Using a stabilized diode-laser spectrometer, we have studied the line profiles of water vapor near 7185.59 cm(-1). With low pressures of pure gas ( View Article and Find Full Text PDF