Visualizing the Formation of High-Entropy Fluorite Oxides from an Amorphous Precursor at Atomic Resolution.

High-entropy oxides (HEOs) have a large tuning space in composition and crystal structures, offering the possibility for improved material properties in applications including catalysis, energy storage, and thermal barrier coatings. Understanding the nucleation and growth mechanisms of HEOs at the atomic scale is critical to the design of their structure and functions but remains challenging. Herein, we visualize the entire formation process of a high-entropy fluorite oxide from a polymeric precursor using atomic resolution gas-phase scanning transmission electron microscopy.