Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility.

Alkyl-PAHs (APAHs) have been identified worldwide, which could rapidly react with chlorine and OH radicals in the atmosphere. In this study, a comprehensive investigation is conducted for SOA generated by a representative alkyl-naphthalene (1-methyl naphthalene, 1-MN) initiated by Cl, including yield, chemical composition, and volatility of SOA. To better understand 1-MN atmospheric oxidation, reaction mechanisms of 1MN with Cl atoms and OH radicals are proposed and compared under different nitrogen oxides (NO) conditions.

Kinetic and mechanism of the reaction between Cl and several mono-methyl branched alkanes.

Branched alkanes are ubiquitous in the troposphere and play an important role in the chemical processes. In this work, the rate constants and products for the reaction of Cl atoms with 3-methylhexane and 2-methylheptane were measured at room temperature (298 ± 0.2 K) and atmospheric pressure using a conventional relative rate method.

Reactions of C-C -Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation.

Long-chain alkanes are a type of intermediate volatility organic compound (IVOC) in the atmosphere and a potential source of secondary organic aerosols (SOAs). C-C -alkylcyclohexanes are important compositions of IVOCs, with considerable concentrations and emission rates. The reaction rate constants and SOA formation of the reactions of C-C -alkylcyclohexanes with Cl atoms were investigated in the present study.

Study on the reaction of 3-methyl-2-butenal and 3-methylbutanal with Cl atoms: kinetics and reaction mechanism.

The reaction of Cl atoms with two C aldehydes (3-methyl-2-butenal and 3-methylbutanal) were investigated by proton-transfer-reaction mass spectrum (PTR-MS) using smog chamber at 298 ± 1 K and 760 Torr. A relative rate method was used to determine the rate constants of the title reactions with m-xylene and trans-2-butene as reference compounds: (3.04 ± 0.

A Combined Experimental and Theoretical Study on the Gas Phase Reaction of OH Radicals with Ethyl Propyl Ether.

The reaction of ethyl propyl ether (EnPE) with OH radicals was studied using proton-transfer-reaction mass spectrum (PTR-MS), and the rate constant was measured at 298 K and atmospheric pressure using the relative rate method: = (1.13 ± 0.09) × 10 cm molecules s.