Nanomaterials (Basel)
November 2024
Curcumin is utilized extensively as Chinese medicine in Asia due to its antioxidant, antimicrobial, and inflammatory activities. However, its use has the challenges of low oral bioavailability and high heat sensitivity. The aim of this research was to produce flexible nano-liposomes containing curcumin using an innovative approach of ethanol injection and Tween 80 to enhance the stability and preservation of curcumin.
View Article and Find Full Text PDFParticulate matter (PMs) from combustion emissions (traffic, power plant, and industries) and the novel coronavirus (COVID-19) pandemic have recently enhanced the development of personal protective equipment against airborne pathogens to protect humans' respiratory system. However, most commercial face masks still cannot simultaneously achieve breathability and high filtration of PMs, bacteria, and viruses. This study used the electrospinning method with polyimide (PI) and polyethersulfone (PES) solutions to form a nanofiber membrane with low-pressure loss and high biocompatibility for high-efficiency bacteria, viruses, and nano-aerosol removal.
View Article and Find Full Text PDFThis study focused on an iron phthalocyanine compound with aligned CNTs on the surface of a carbon felt electrode (FePc/CNT/C) to enhance the bio-electro-Fenton microbial fuel cell system cathodes reaction rate of hydrogen peroxide and the electrical plate. Experiments of polarization curves and power density, decolorization of Reactive Black 5 (RB5), and scanning electron microscopy (SEM) measured the characteristics of the cathode plate. FePc/CNT/C presented better electrical properties (open-circuit voltage, maximum current density, and maximum power density) than that of CNT/C and C, as FePc is a catalyst and its planar structure could easily adhere to CNT to enhance the reduction reaction at the cathode and provide higher specific surface area.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
March 2018
Recyclable magnetites with thioureido group (poly-allyl-thiourea/oleic acid/magnetite, PAT-adsorbent) and amine functional group (ethylenediamine/methyl methacrylate/oleic acid/magnetite, EDA-adsorbent) were synthesized by modifying magnetite with oleic acid, methyl methacrylate, allyl thiourea and ethylenediamine. PAT-adsorbent and EDA-adsorbent were used and compared for adsorption of copper ions in a batch system due to the existence of amino group (-NH2) both on thioureido group and amine functional group. The kinetics of both PAT-adsorbent and EDA-adsorbent were evaluated utilizing pseudo-first-order and pseudo-second-order kinetic models.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
June 2015
In this work, magnetic particles were firstly protected by oleic acid, and then polymers, the polymers was prepared with allyl-thiourea as the functional monomer, ethyleneglycol dimethacrylate as the cross-linking agent, 2,2-azobisisobutyronitrile as the initiator, and acetonitrile as the solvent. The magnetic polymers were analyzed by FT-IR, X-ray diffraction, and a vibrating sample magnetometer to obtain the morphological and magnetic properties. The adsorption of phosphate on the magnetic polymers was investigated, including pH effect, initial concentration, and temperature.
View Article and Find Full Text PDFA liquid fertilizer obtained through food-waste composting can be used for the preparation of a dissolved organic carbon (DOC) solution. In this study, we used the DOC solutions for the remediation of a Zn-contaminated soil (with Zn concentrations up to 992 and 757 mg kg(-1) in topsoil and subsoil, respectively). We then determined the factors that affect Zn removal, such as pH, initial concentration of DOC solution, and washing frequency.
View Article and Find Full Text PDFA magnetic adsorbent, amine-functionalized silica magnetite (NH2-Al/SiO2/Fe3O4), has been synthesized to behave as an cationic adsorbent by adjusting the pH value of the aqueous solution to make amino groups protonated. NH2-Al/SiO2/Fe3O4 was used to adsorb phosphate ions in an aqueous solution in a batch system, and the maximum adsorption were found to occur at pH 3.0.
View Article and Find Full Text PDFMagnetic polyvinyl alcohol adsorbent M-PVAL was employed to remove and concentrate dimethyl phthalate DMP. The M-PVAL was prepared after sequential syntheses of magnetic Fe3O4 (M) and polyvinyl acetate (M-PVAC). The saturated magnetizations of M, M-PVAC, and M-PVAL are 57.
View Article and Find Full Text PDFThis study investigates the feasibility of applications of the plasma surface modification of photocatalysts and the removal of toluene from indoor environments. N-doped TiO2 is prepared by precipitation methods and calcined using a muffle furnace (MF) and modified by radio frequency plasma (RF) at different temperatures with light sources from a visible light lamp (VLL), a white light-emitting diode (WLED) and an ultraviolet light-emitting diode (UVLED). The operation parameters and influential factors are addressed and prepared for characteristic analysis and photo-decomposition examination.
View Article and Find Full Text PDFThis study is to optimize the multi-quality performance of magnetic catalyst/ozone process by combining a technique for order performance by similarity to ideal solution (TOPSIS) with the Taguchi method, which simultaneously has the best decomposition rate constant of benzoic acid and removal rate constant of total organic carbon (TOC). The optimal experimental parameters were pH of 7, initial concentration of 75 ppm and catalyst loading of 0.05 g/L.
View Article and Find Full Text PDFThe photocatalytic oxidation of titanium dioxide is conducted in a suspension of submicrometer-sized particles, and an additional separation step is required to recover these catalyst particles from treated water, which presents a major drawback in treating wastewater. In this study, magnetic photocatalysts of spinel structure Fe3O4 coated with SiO2 and TiO2 by employing various heat treatments were synthesized and their characterization was carried out by thermogravimetric analysis, X-ray diffraction, vibrating sample magnetometry, and Fourier transform infrared spectroscopy. Furthermore, the reaction behavior in photocatalytic processes involving photocatalysts of porous composite for treating wastewater were analyzed to enhance their activity and recovery.
View Article and Find Full Text PDFA magnetic adsorbent, amine-functionalized silica magnetite (NH(2)/SiO(2)/Fe(3)O(4)), has been synthesized to behave as an anionic or cationic adsorbent by adjusting the pH value of the aqueous solution to make amino groups protonic or neutral. NH(2)/SiO(2)/Fe(3)O(4) were used to adsorb copper ions (metal cation) and Reactive Black 5 (RB5, anionic dye) in an aqueous solution in a batch system, and the maximum adsorption were found to occur at pH 5.5 and 3.
View Article and Find Full Text PDFThis study explored dye decolorization and bioelectricity generation of indigenous Proteus hauseri ZMd44 for dye-bearing wastewater treatment. Chemical structures of azo dyes apparently affected the performance of dye biodecolorization. Additions of diazo dye C.
View Article and Find Full Text PDFThis study investigated the pozzolanic reactions and engineering properties of waste brick-blended cements in relation to various replacement ratios (0-50%). The waste brick consisted of SiO(2) (63.21%), Al(2)O(3) (16.
View Article and Find Full Text PDFParticles are often too small to be separated from a reaction system and recycled, especially in wastewater treatment via a catalytic ozonation process. Thus, the objective of this study was to prepare a magnetic catalyst (SiO(2)/Fe(3)O(4)) that can be recycled by using an external magnetic field. The effects of the characteristics of the magnetic catalyst, pH values, catalyst dosage, and initial concentration of Reactive Black 5 (RB5) on mineralization efficiency of the magnetic catalyst/H(2)O(2)/O(3) process were also investigated.
View Article and Find Full Text PDFWine-processing waste sludge (WPWS) has been shown to have powerful potential for sorption of some heavy metals (i.e., chromium, lead and nickel) in single-component aqueous solutions.
View Article and Find Full Text PDFVolatile organic compounds (VOCs) are the cause of indoor air pollution and are readily emitted from furniture and cleaning agents. In Taiwan, the concentrations of indoor VOCs range roughly from 1 to 10 ppm. It is important to effectively reduce indoor VOC emissions and establish the implementation of long-term, low-cost, controlled techniques such as those found in the ultraviolet/titanium dioxide (UV/TiO2) control systems.
View Article and Find Full Text PDFThis study investigated the surface modification of photocatalyst and photodecomposition of formaldehyde from indoor pollution source. This study explored the feasibility of the application of the ultraviolet light emitting diode (UVLED) instead of the traditional ultraviolet (UV) lamp to treat the formaldehyde. The photocatalytic decomposition of formaldehyde at various initial concentrations was elucidated according to the Langmuir-Hinshelwood model.
View Article and Find Full Text PDFThis study evaluated the performance of a photoreactor packed with TiO2/glass, TiO2 immobilized on glass beads, initiated by UV irradiation, denoted as UV/TiO2/glass, to decompose di-n-butyl phthalate (DBP) in an aqueous solution. The photodegradation rate of DBP by this UV/TiO2/glass process was found to obey pseudo first-order kinetics represented by the Langmuir-Hinshelwood model. The experimental results of this study show that the influence of pH value of an aqueous solution to reaction rate was negligible at the pH values 4.
View Article and Find Full Text PDFA waste sludge produced from a wine-processing wastewater treatment process was used as an adsorbent to removal of heavy metal-lead(II) from aqueous solution. Results of kinetic experiments demonstrated that the adsorption was effective and rapid. Four different kinds of adsorption kinetic models (i.
View Article and Find Full Text PDFThis study evaluated the performance of photo-Fenton reaction initiated by the UV irradiation with H(2)O(2)/Fe(3+), denoted as UV/H(2)O(2)/Fe(3+), to decompose di-n-butyl phthalate (DBP) in the aqueous solution. The concentration of total organic carbon (TOC) was chosen as a mineralization index of the decomposition of DBP by the UV/H(2)O(2)/Fe(3+) process. A second-order kinetic model with respect to TOC was adequately adopted to represent the mineralization of DBP by the UV/H(2)O(2)/Fe(3+) process.
View Article and Find Full Text PDFA method was used to investigate the potential for using water clarifier sludge to remove copper in a fluidized-bed reactor (FBR). This study was conducted to evaluate the removal of copper in an aquatic system without prior treatment. Chemical analyses of water clarifier sludge through inductively coupled plasma-atomic emission spectrophotometry indicated that silicon, aluminum and iron oxides made up more than 84% of this average composition, similar to the composition of clay.
View Article and Find Full Text PDFBasic oxygen furnace slag (BOF slag) is a solid waste arisen from the steel making process. FeO is one of the major components of BOF slag. The FeO-containing property of BOF slag makes it possible to catalyze the Fenton reaction.
View Article and Find Full Text PDFThis study investigates the ozonation of 2-naphthalenesulfonate (2-NS) combined with UV radiation in the electroplating solution. 2-NS is commonly used as a brightening and stabilization agent in the electroplating solution. Semibatch ozonation experiments were conducted under various reaction conditions to study the effects of ozone dosage and UV radiation on the oxidation of 2-NS.
View Article and Find Full Text PDFJ Colloid Interface Sci
May 2004
Wine processing waste sludge has been shown to be an effective adsorbent for the adsorption of Cr(III) from aqueous solution. The sludge has been characterized by scanning electron microscopy (SEM) and energy dispersive X-rays (EDX). The effect of pH, initial concentration of Cr(III), sludge particle size, and temperature on the adsorption studied.
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