Developing ultraviolet (UV), visible (Vis) and near-infrared (NIR) responsive photocatalysts for Cr(VI) reduction is valuable. Herein, a 0-dimensional/1-dimensional (0D/1D) S-scheme AgS/BiSI hetero-structured photocatalyst was successfully synthesized, which displays greatly enhanced Cr(VI) removal activity either under UV, Vis or NIR light irradiation. In-situ characterization technique and theoretical calculation confirm that an internal electric field (IEF), directing from AgS to BiSI, exists between the interface, which facilitates the spatial-oriented separation of photoirradiated carriers.
View Article and Find Full Text PDFManganese dioxide (MnO) nanomaterials have shown excellent performance in catalytic degradation and other fields because of their low density and great specific surface area, as well as their tunable chemical characteristics. However, the methods used to synthesize MnO nanomaterials greatly affect their structures and properties. Therefore, the present work systematically illustrates common synthetic routes and their advantages and disadvantages, as well as examining research progress relating to electrochemical applications.
View Article and Find Full Text PDFSoil washing techniques can effectively remove soil polybrominated diphenyl ethers (PBDEs), but further removal of PBDEs from washing effluent is disrupted by environmental factors and coexisting organic matter. Hence, this work prepared novel magnetic molecularly imprinted polymers (MMIPs) to selectively remove PBDEs in soil washing effluent and recycling surfactants, with FeO nanoparticles as the magnetic core, methacrylic acid (MAA) as the functional monomer, and ethylene glycol dimethacrylate (EGDMA) as the cross-linker. Later, the prepared MMIPs were applied to adsorb 4,4'-dibromodiphenyl ether (BDE-15) in Triton X-100 soil-washing effluent and characterized by scanning electron microscopy (SEM), infrared spectrometry (FT-IR), nitrogen adsorption and desorption experiments.
View Article and Find Full Text PDFSurfactant enhanced elution is an effective method for removing hydrophobic organic pollutants from soils. The key to the development of leaching technology is selective removal of targeted pollutants in soil washing effluent and recycling of surfactant solutions. In this study, a molecular imprinting technique was applied to selectively sorb polybrominated diphenyl ethers (PBDEs) in soil washing effluent.
View Article and Find Full Text PDFJarosite is an important scavenger for arsenic (As) due to its strong adsorption capacity and ability to co-precipitate metal(loid)s in acid mine drainage (AMD) environments. When subjected to natural organic matter (NOM), metastable jarosite may undergo dissolution and transformation, affecting the mobility behavior of As. Therefore, the present study systematically explored the dissolution and transformation of jarosite, and the consequent redistribution of coprecipitated As(V) under anoxic condition in the presence of a common phenolic acid-gallic acid (GA).
View Article and Find Full Text PDFIn recent years, persulfate (PS) has been widely studied as a promising oxidant. In this work, a new K-FeO catalyst was synthesized a facile impregnation method. K-FeO samples were utilized as heterogeneous photocatalysts for the degradation of aquatic organic pollutants (rhodamine, RhB, and ciprofloxacin, CIP).
View Article and Find Full Text PDFIn this work, a magnetic ion imprinted polymer (MIIP) with specific recognition capability toward cadmium was prepared by a sol-gel method using waste beer yeast, which is a macromolecule biomass, as a functional monomer. The obtained Cd(ii)-MIIP was characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and adsorption experiments. Then, a MIIP adsorbent based magnetic solid phase extraction (MSPE)-graphite furnace atomic absorption (GFAA) method was established to analyze the cadmium content in food and environmental samples.
View Article and Find Full Text PDFBioresour Technol
February 2011
The alkaline phosphatase activities (APA) and phosphorus fractions in activated sludge during wastewater treatment were studied. Our results showed that the phosphorus concentration and fractions in activated sludge were highly correlated with the characteristics of influents. Inorganic phosphorus (IP) and non-apatite inorganic phosphorus (NAIP) were the main phosphorus fractions of sludge.
View Article and Find Full Text PDFThe influence of metal ions, anions, ortho-phosphate, polyphosphate and organic phosphorus on the activity and kinetics of alkaline phosphatase in aerobic activated sludge taken from a local municipal wastewater treatment plant was investigated. Results suggested that there were three impact models of heavy metals on alkaline phosphatase activity (APA) and most inorganic anions were relatively innocuous at concentrations from 0 to 5.0mM.
View Article and Find Full Text PDFA series of pot and field experiments and field demonstrations showed that in comparing with the commonly used specific-fertilizers containing same amounts of nutrients, single basal application of rice-specific controlled release fertilizer could increase the use efficiency of N and P by 12.2% - 22.7% and 7.
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