Electrochemical Denitrative Cyclization Driven by Alternating Polarity.

Alternating current electrolysis has emerged as a promising technique for addressing challenging redox reactions that are otherwise difficult or impossible for direct current electrolysis. Under mild and transition-metal-free reaction conditions, a general electrochemical denitrative cyclization of nitroarenes was developed to access various cyclic sulfone-containing derivatives of biological significance. The key to success lies in the facile manipulation of multiple redox events upon rapid alternating polarity switching to enhance the selectivity and efficiency.

Self-referenced distribution of millimeter waves over 10 km optical fiber with high frequency stability.

In this Letter, an actively stabilized photonic system for millimeter-wave (mmW) signal distribution is proposed and experimentally demonstrated. By interlocking two baseband RF signals obtained from a dual-heterodyne detection through a single carrier compensation module, the phase fluctuations induced by the fiber transmission link is suppressed without the need of a local frequency reference. In the proof-of-concept experiment, a 108 GHz mmW is transmitted over a 10 km fiber link with a performance matching that of the back-to-back case.