Binary and nanostructured NiMn perovskite fluorides as efficient electrocatalysts for urea oxidation reaction.

Urea electrolysis holds tremendous promise to provide green and sustainable energy and environmental solutions, because it can simultaneously remedy urea-containing wastewater and provide energy-saving hydrogen. However, the development of this emerging technology remains challenging mainly due to a dearth of high-performance electrocatalysts for efficient urea oxidation reaction (UOR). Perovskite fluorides have the advantages of intrinsic 3D diffusion pathways, robust architecture, and tunable chemical composition, thus receiving increasing attention in many applications.