The effects of the concentration of NaCl solutions on the corrosion resistance of granular CoCrFeNiV and dendritic CrFeCoNiV high-entropy alloys were studied. The polarization behavior of CoCrFeNiV and CrFeCoNiV alloys in deaerated 0.5 M and 1 M sodium chloride solution at different temperatures was measured by a constant galvanostatic/potentiometric.
View Article and Find Full Text PDFCrFeCoNiV high-entropy alloys were prepared by arc-melting, and the microstructures and corrosion properties of these alloys were studied. The CrFeCoNiV alloy had a granular structure; the matrix was a face-centered cubic (FCC) structure, and the second phase was a σ phase with a tetragonal structure. The CrFeCoNiV alloy had a dendritic structure; the dendrites in this alloy showed an FCC phase, and the interdendrities had a eutectic structure of FCC and σ phases.
View Article and Find Full Text PDFThe present work systematically investigated the effects of niobium and molybdenum on the microstructures and corrosion properties of high-entropy CrFeCoNiNbMo and CrFeCoNiNbMo alloys, the maximum content of (Nb + Mo) was 20 at.%. All of the alloys were prepared by arc melting under an argon atmosphere.
View Article and Find Full Text PDFFeCoNiMo and CrFeCoNiMo equimolar alloys were prepared by arc-melting. The microstructures of the as-cast alloys were examined by SEM, HREM and XRD; and a potentiodynamic polarization test of the as-cast alloys was undertaken to evaluate the corrosion resistance in the solutions. Results showed that both of FeCoNiMo and CrFeCoNiMo equimolar alloys had a dendritic structure.
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October 2021
The composition of the CrFeCoNiNb high-entropy alloy was selected from the FCC phase in a CrFeCoNiNb alloy. The alloy was melted in an argon atmosphere arc-furnace, followed by annealing in an air furnace. The dendrites of the alloy were in the FCC phase, and the eutectic interdendrites of the alloy comprised HCP and FCC phases.
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November 2020
This paper investigates the effects of Ta content on the microstructures, hardness and corrosion behavior of as-cast CoCrFeNiTa alloys. The results indicate that the addition of Ta can change the microstructures of these alloys to dual-phased structures (FCC + HCP), as well as increasing their hardness. This study uses constant galvanostatic/potentiometric methods to measure the polarization curves of CoCrFeNiTa, CoCrFeNiTa and CoCrFeNiTa alloys in deaerated 1 M sodium chloride solution at different temperatures.
View Article and Find Full Text PDFThis work studied the effect of niobium-content on the microstructures, hardness, and corrosion properties of CrFeCoNiNb alloys. Results indicated that the microstructures of these alloys changed from granular structures (CrFeCoNi alloy) to the hypereutectic structures (CrFeCoNiNb and CrFeCoNi alloys), and then to the hypoeutectic microstructures (CrFeCoNiNb and CrFeCoNi alloys). The lattice constants of the major two phases in these alloys, fcc and Laves phases (hcp), increased with the increasing of Nb-content because of solid-solution strengthening.
View Article and Find Full Text PDFEntropy (Basel)
August 2018
The effects of niobium and molybdenum additions on the microstructures, hardness and corrosion behaviors of CrFeCoNi(Nb,Mo) alloys were investigated. All of the CrFeCoNi(Nb,Mo) alloys displayed dendritic microstructures. The dendrites of CrFeCoNiNb and CrFeCoNiNbMo alloys were a hexagonal close packing (HCP) phase and the interdendrites were a eutectic structure of HCP and face-centered cubic (FCC) phases.
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December 2017
This study investigates the effects of niobium and molybdenum on FeCoNi alloy, including on the microstructures and hardness of FeCoNiNbMo and FeCoNiNb alloys, and the polarization behaviors of these alloys in 1 M sulfuric acid and 1 M sodium chloride solutions. The results in this study indicate that both FeCoNiNbMo and FeCoNiNb alloys had a dual-phased dendritic microstructure; all of the phases in these alloys were solid solution phases, and no ordering was observed. Therefore, the solid solution effect significantly increased the hardness of these two alloys; in particular, FeCoNiNb alloy had the highest hardness of the alloys of interest.
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September 2017
This study investigated the effects of Ti content and vacuum annealing on the microstructure evolution of TiFeCoNi (x = 0, 0.5, and 1) thin films and the underlying mechanisms. The as-deposited thin film transformed from an FCC (face center cubic) structure at x = 0 into an amorphous structure at x = 1, which can be explained by determining topological instability and a hard ball model.
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