Publications by authors named "Chun-Chuan Kao"

Currently, direct electrolysis of seawater for green hydrogen production is primarily focused on neutral and alkaline systems. However, the precipitation of calcium and magnesium ions restricts the advancement of this technology. An acidic system can effectively address this issue.

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Article Synopsis
  • Aqueous zinc-iodine batteries (ZIBs) are gaining popularity due to their efficient energy conversion and fast reaction rates, although the common two-electron types struggle with low energy density.
  • Recent advancements in four-electron ZIBs have improved energy density but face challenges with redox reversibility and issues like polyiodide shuttling.
  • The review discusses the mechanisms, limitations of ZIBs, emphasizes the importance of zinc utilization rates, and suggests solutions for recycling iodine electrodes to support sustainable energy storage.
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Improving kinetics of solid-state sulfide conversion in sulfur cathodes can enhance sulfur utilization of metal-sulfur batteries. However, fundamental understanding of the solid-state conversion remains to be achieved. Here, taking potassium-sulfur batteries as a model system, we for the first time report the reducing overpotential of solid-state sulfide conversion via the meta-stable S intermediates on transition metal single-atom sulfur hosts.

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Aqueous Zn-ion batteries hold practical promise for large-scale energy storage because of the safety and affordability of aqueous-based electrolytes; in addition, the manufacturing process is significantly simplified by direct employment of Zn metal as an anode. However, hydrogen evolution due to near-surface water dissociation has hindered large-scale applications of them. Here, we report the suppression of the hydrogen evolution reaction via a CuN-coordinated graphitic carbonitride (CuN-CN) anticatalytic interface to achieve highly efficient aqueous Zn-ion batteries.

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