Nature of Disordering in γ-Ga_{2}O_{3}.

Polymorphs commonly exist for various materials, enabling phase engineering for diverse material properties. While the crystal structures of different polymorphs can, in principle, be experimentally characterized, interpreting and understanding complex crystal structures can be very challenging. Using Ga_{2}O_{3} as a prototype, here we show that the crystal structure of γ-Ga_{2}O_{3} has long been misinterpreted from either theory or experiment.

Critical Role of Configurational Disorder in Stabilizing Chemically Unfavorable Coordination in Complex Compounds.

The crystal structure of a material is essentially determined by the nature of its chemical bonding. Consequently, the atomic coordination intimately correlates with the degree of ionicity or covalency of the material. Based on this principle, materials with similar chemical compositions can be successfully categorized into different coordination groups.

Computational Screening of Promising Deep-Ultraviolet Light Emitters.

Deep-ultraviolet (DUV) light sources are technologically highly important, but DUV light-emitting materials are extremely rare; AlN and its alloys are the only materials known so far, significantly limiting the chemical and structural spaces for materials design. Here, we perform a high-throughput computational search for DUV light emitters based on a set of carefully designed screening criteria relating to the sophisticated electronic structure. In this way, we successfully identify 5 promising material candidates that exhibit comparable or higher radiative recombination coefficients than AlN, including BeGeN, MgNF, KCaBr, KHS, and RbHS.

Stress-matched laminated thin film of SiON/SiO/ SiON for enhanced encapsulation of organic light-emitting devices.

The laminated structure of thin-film encapsulation (TFE) plays an important role for the reliability of organic light-emitting devices (OLEDs). In previous studies of TFE-structures, only the density of the films and the gas-barrier properties were taken into account, while a potential internal stress in the film was largely neglected. Internal stress issues can lead to cracks, warping, and delamination, which affect the performance of the encapsulation layer significantly.

Excellent Gas Sensing of CdS Nanowires Decorated with Ag Nanoparticles.

In this study, CdS nanowires (NWs)/Ag nanoparticle materials (CdS@Ag) with Schottky junction were synthesized by a simple process. The Ag nanoparticles with a diameter of 3-10 nm were uniformly scattered on the surface of CdS NWs with an average diameter of 30 nm. The gas sensing properties and the effect of Ag content and relative humidity on the ethanol sensing properties of CdS NWs were investigated in detail.

Facilitated extrinsic majority carrier depletion and photogenerated exciton dissociation in an annealing-free ZnO:C photodetector.

Applications of ZnO in photodetectors are limited by the great quantity of extrinsic majority carriers due to structural defects and difficult exciton dissociation due to the large exciton binding energy; these generally lead to a higher dark current (Id) and lower light current (Il), severely degrading the responsivity and detectivity. C dots are incorporated into an annealing-free ZnO layer to innovatively construct a local built-in electric field (Ebi) using the difference in the work functions; this simultaneously overcomes the drawbacks of the pristine ZnO photosensitive layer. In dark, the extrinsic majority carrier of ZnO is depleted around the incorporated C dots due to the self-depleting effect; thus, the Id decreases.

Structural and spectroscopic studies on Pt.Pt and pi-pi interactions in luminescent multinuclear cyclometalated platinum(II) homologues tethered by oligophosphine auxiliaries.

The synthesis and structural, spectroscopic, and electrochemical properties of a series of trinuclear tridentate cyclometalated platinum(II) complexes tethered by bis(diphenylphosphinomethyl)phenylphosphine (dpmp) have been studied and compared with their mono- and binuclear homologues and a propeller-like congener. The X-ray crystal structures of several derivatives show the presence of a variety of intramolecular Pt.Pt, pi-pi, and C-H.