PVDF/ZnO/CuS photocatalysts with ZnO/CuS heterojunctions were synthesized electrospinning, hydrothermal, and ion-exchange techniques. As matrix materials, electrospun PVDF nanofibers are easy to be recycled and reused. ZnO nanorods anchored on PVDF nanofiber with high specific surface area provide abundant active reaction sites for photocatalysis.
View Article and Find Full Text PDFTo improve the adsorption performance of carbon materials, novel ZnO nanoparticle-incorporated porous carbon nanofibers (Zn@PCNFs) were prepared via an electrospinning technique. A facile one-step fabrication strategy was proposed to simultaneously complete the carbonization of a peroxided polyacrylonitrile framework, the activating treatment caused by ZnO reducing to Zn, and the pore generation caused by evaporation of reduced Zn with a low melting point. The influences of the pH, ion category, and concentration on methylene blue adsorption were investigated.
View Article and Find Full Text PDFIn this study, amino hyperbranched polymers (HBP)-grafted polyacrylonitrile (PAN) fiber was prepared through an amidation reaction in an autoclave. The prepared PAN-G-HBP fiber can complex Ag through amino groups of amino HBP, and in a hot steaming condition, Ag can be converted to Ag0 through the reducibility of HBP. PAN-G-HBP and Ag nanoparticles (NPs)-coated fibers were then characterized through FTIR, UV-VIS DRS, FE-SEM, EDS, XPS and antibacterial measurement.
View Article and Find Full Text PDFHerein, the amino-capped TiO nanoparticles were synthesized using tetrabutyl titanate and amino polymers by a two-step sol-gel and hydrothermal method technique for the fabrication of functional cotton fabric. The prepared TiO nanoparticles and the treated cotton fabric were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), field emission scanning electron microcopy (FE-SEM) photocatalytic and antibacterial measurement. The results indicate the typical characteristic anatase form of the amino-capped TiO NPs with an average crystallite size of 14.
View Article and Find Full Text PDFIn order to fabricate antibacterial cotton fabric with excellent antibacterial property and laundering durability, amino functional silver nanoparticles (Ag NPs) were prepared by one-step reaction with amino-terminated hyperbranched polymer (HBP-NH(2)) and grafted on the oxidized cotton fabric subsequently. The synthesized amino functional Ag NPs and Ag NPs grafted oxidized cotton fabric (Ag-GOCF) were characterized which indicated that the average size of Ag NPs was 10.8 nm with narrow size distribution and the Ag NPs have been grafted on the cotton fabric.
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