Regulable high-contrast mechanofluorochromic enhancement behaviour based on substituent effects.

Herein, a facile strategy was established to build mechanoresponsive luminogens with high sensitivity to substituents and positional effects. Even in slightly different structures, distinct optical phenomena, including fluorescence efficiency and mechano-responsive properties, were clearly present. Outstanding mechanical-induced emission enhancement (5-100 times) properties and reversibility makes for promising applications in pressure sensors and OLEDs.

Precise Synthesis of Organic Cocrystal Alloys with Full-Spectrum Emission Characteristics for the Stepless Color Changing Display.

Organic luminescent materials are indispensable in optoelectronic displays and solid-state luminescence applications. Compared with single-component, multi-component crystalline materials can improve optoelectronic characteristics. This work forms a series of full-spectrum tunable luminescent charge-transfer (CT) cocrystals ranging from 400 to 800 nm through intermolecular collaborative self-assembly.

A comparative study on optical properties of pyrene-fused [4]helicenes and vinyl precursors.

Polycyclic aromatic hydrocarbon-fused [n]helicene derivatives (PAH-fused [n]helicenes) have been widely investigated due to their excellent photoelectric and chiroptical properties. Herein, a series of pyrene-fused helicenes were synthesized by a photocyclization reaction and characterized by H/C NMR spectroscopy and single crystal X-ray diffraction. All compounds and their vinyl precursors were studied as emitting materials.

Synthesis and bioactivity evaluation of novel nuciferine derivatives with antihyperuricemia and nephroprotective effects.

Hyperuricemia is a common metabolic disease with a series of complications. Nuciferine, a typical aporphine alkaloid natural compound extracted from the leaves of Nelumbo nucifera Gaertn., was confirmed to have an antihyperuricemia effect.

Theoretical study and experimental validation on the optical emission processes in "free" and "locked" pyrazine derivatives.

The excited-state properties of the "free" and "locked" pyrazine derivatives are investigated in solution. DCFP with "free" phenyls is theoretically calculated to be non-emissive due to the non-radiative energy dissipation through strong Duschinsky rotation effect, in agreement with the available experimental result. Surprisingly, DCBP with "bi-locked" phenyls is also calculated to be nonluminous.

Pyrene-Based Approach to Tune Emission Color from Blue to Yellow.

The development of functionalized, luminescent, pyrene-based monomers has been and continues to be an area of great interest in terms of the design and fabrication of optical and electronic devices. Herein, a facile strategy to tune the emission color of pyrene-based chromophores has been established by simple functional group modification at the para position to the diphenylamino on the donor building block. Intriguing photophysical properties were obtained and are described both in different solutions and in the solid state.

An Unprecedented Photochemical Reaction for Anthracene-Containing Derivatives.

A series of anthracene-containing derivatives have been synthesised and characterised. The photochemical behaviour of these derivatives have been investigated by H NMR spectroscopy. An unprecedented photolysis reaction for anthracene-containing derivatives was observed in the case of anthracenes directly armed with a -CH O-R group upon UV irradiation.

A novel fluorescence "on-off-on" chemosensor for Hg(2+)via a water-assistant blocking heavy atom effect.

Upper rim pyrene-functionalized hexahomotrioxacalix[3]arene L was synthesized via Click chemistry, and its fluorescence behaviors toward several common metal cations were investigated. L exhibited a significant fluorescence quenching response to Hg(2+) in CH3CN solution, which was unaffected by the coexistence of other competitive metal cations. Thus, L can be utilized as a highly selective and sensitive fluorescent chemosensor for Hg(2+) with a detection limit in the nM level.

A Hemimethyl-Substituted Cucurbit[7]uril Derived from 3α-Methyl-glycoluril.

A novel hemimethyl-substituted cucurbit[7]uril (HMeQ[7]) derived from 3α-methyl-glycoluril has been prepared. HMeQ[7] is readily soluble in both water and dimethyl sulfoxide (DMSO) and displays not only host-guest interaction properties similar to those of the normal cucurbit[7]uril but also unusual properties in DMSO.

Interaction of Ln with Methyl-Substituted Cucurbit[n]urils (n=5,6) Derived from 3α-Methyl Glycoluril.

The interactions between a series of lanthanide cations (Ln ) and methyl-substituted cucurbiturils (SPMeQ[5] and SHMeQ[6]) derived from a 3α-methyl glycoluril have been investigated. Single-crystal X-ray diffraction analysis revealed that both SPMeQ[5] and SHMeQ[6] selectively interact with certain lanthanide ions. SPMeQ[5] forms coordination capsules in the presence of [CdCl ] .