The white matter characteristic of the genu of corpus callosum coupled with pain intensity and negative emotion scores in patients with trigeminal neuralgia: a multivariate analysis.

Background: Trigeminal neuralgia (TN) is a chronic neuropathic pain disorder that not only causes intense pain but also affects the psychological health of patients. Since TN pain intensity and negative emotion may be grounded in our own pain experiences, they exhibit huge inter-individual differences. This study investigates the effect of inter-individual differences in pain intensity and negative emotion on brain structure in patients with TN and the possible pathophysiology mechanism underlying this disease.

An enhanced electrocatalytic oxygen evolution reaction by the photothermal effect and its induced micro-electric field.

Promoting better thermodynamics and kinetics of electrocatalysts is key to achieving an efficient electrocatalytic oxygen evolution reaction (OER). Utilizing the photothermal effect and micro-electric field of electrocatalysts is a promising approach to promote the sluggish OER. Herein, to reveal the relationship of the photothermal effect and its induced micro-electric field with OER performance, NiS coupled NiFe(OH) on nickel foam (NiS@NiFe(OH)/NF) is synthesized and subjected to the OER under near-infrared (NIR) light.

Construction of MoB@LDH heterojunction and its derivates through phase and interface engineering for advanced supercapacitor applications.

Layered double hydroxide (LDH) has been attracted widespread attention in supercapacitor due to their unique layered structure and associated advantages. However, the inherent limitations of low electrical conductivity and reaction kinetics rate of LDH restrict its widespread application. Various modification techniques, such as heterojunction formation, phosphorization and introduction of phosphorus vacancies, are employed to modify LDH with the goal of improving the electrochemical performance.

C-Rich Carbon Nitride Conjugated Polymer Enabling Ion-Migration-Induced Precise Electrochromic Display.

The development of electrochromic (EC) displays has been in the challenge of displaying precise patterns, such as characters or high-resolution images of small size. High-performance EC materials as well as efficient, precise-display strategies are still urgent. To enable a microfactor-guided strategy for highly precise display, I/I ion-migration-induced localized electrochromism is developed in an EC device based on the C-rich polymeric carbon nitride (CPCN).

Chirality dependent electromechanical properties of single-layer MoS under out-of-plane deformation: a DFT study.

2D transition metal dichalcogenides (TMDs) demonstrate significant promise in logic circuits and optoelectronic devices because of their unique structures and excellent semiconductor properties. However, they inevitably undergo out-of-plane deformation during practical applications due to their ultra-thin structures. Recent experiments have shown that out-of-plane deformation significantly affects the electronic structures of 2D TMDs.

The explanation of abnormal thermal quenching of the charge transfer band based on thermally coupled levels and applications as temperature sensing probes.

Because of thermal quenching, conventional luminescent materials suffer from severe problems when employed at high temperatures. Based on the thermally coupled energy levels (TCLs) of rare-earth ions, we report and explain an abnormal thermal quenching phenomenon in the excited state of the charge transfer band (CTB), which is expected to bring out a solution to the problems of the low sensitivity of temperature-sensing materials and applications at high temperature. Temperature-dependent excitation spectra of Er or Eu-doped CaMoO, CaWO, and LuVO phosphors are recorded.

Atomic Scale Optimization Strategy of Al-Based Layered Double Hydroxide for Alkali Stability and Supercapacitors.

The pseudocapacitor material is easily decomposed when immersed in alkaline solution for a long time. Hence, it is necessary to find a strategy to improve the alkali stability of pseudocapacitor materials. In addition, the relationship between alkali stability and electrochemical performance is still unclear.

Research status and development of microbial induced calcium carbonate mineralization technology.

In nature, biomineralization is a common phenomenon, which can be further divided into authigenic and artificially induced mineralization. In recent years, artificially induced mineralization technology has been gradually extended to major engineering fields. Therefore, by elaborating the reaction mechanism and bacteria of mineralization process, and summarized various molecular dynamics equations involved in the mineralization process, including microbial and nutrient transport equations, microbial adsorption equations, growth equations, urea hydrolysis equations, and precipitation equations.

A multidimensional rational design of nickel-iron sulfide and carbon nanotubes on diatomite via synergistic modulation strategy for supercapacitors.

Based on their characteristics, transition metal layered double hydroxides have been of great scientific interest for their use in supercapacitors. Up until now, severe aggregation and low intrinsic conductivity have been the major hurdles for their application. In this work, nickel-iron sulfide nanosheets (NiFeSx) and carbon nanotubes (CNTs) were synthesized on diatomite using chemical vapor deposition and a two-step hydrothermal method to overcome these challenges.

High-rate asymmetrical supercapacitors based on cobalt-doped birnessite nanotubes and Mn-FeOOH nanotubes.

Co-Doped MnO2 nanotubes (Co-MnO2-5) were prepared as the positive electrode of supercapacitors via a simple one-step hydrothermal method. Co doping and one-dimensional tunneling of nanotubes result in low internal resistance and good ionic contact, enhancing the conductivity and electrochemical performance of the electrodes.

Assembling a double shell on a diatomite skeleton ternary complex with conductive polypyrrole for the enhancement of supercapacitors.

Double shell FeOOH/PPy on a diatomite ternary complex was assembled via two-step hydrothermal and in situ polymerization routes. The polymerization process generates chemical bonding and introduces oxygen vacancies and mesopores, enhancing the conductivity and electrochemical properties of the electrodes and ensuring structural stability.

Tuning the Bifunctional Oxygen Electrocatalytic Properties of Core-Shell CoO@NiFe LDH Catalysts for Zn-Air Batteries: Effects of Interfacial Cation Valences.

The rational design of excellent electrocatalysts is significant for triggering the slow kinetics of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in rechargeable metal-air batteries. Hereby, we report a bifunctional catalytic material with core-shell structure constructed by CoO nanowire arrays as cores and ultrathin NiFe-layered double hydroxides (NiFe LDHs) as shells (CoO@NiFe LDHs). The introduction of CoO nanowires could provide abundant active sites for NiFe LDH nanosheets.

Acid-salt treated CoAl layered double hydroxide nanosheets with enhanced adsorption capacity of methyl orange dye.

In this study, the ultra-thin CoAl layered double hydroxide (LDH) nanosheets with Cl intercalation were prepared by a hydrothermal method following acid-salt treatment. The morphology, structure and composition information of CoAl LDHs were identified by a variety of characterization methods including SEM, XRD, XPS, FT-IR, and BET. The effects of initial adsorbent concentration, pH, competitive anions, and temperature were also measured.

Design and fabrication of hydrotalcite-like ternary NiMgAl layered double hydroxide nanosheets as battery-type electrodes for high-performance supercapacitors.

Hydrotalcite is an abundant mineral in nature and can be cost-effectively prepared in the laboratory, but there is almost no discussion about its application in the field of supercapacitors. Herein, hydrotalcite-like ternary NiMgAl LDHs with unique ultrathin nanosheets were designed and fabricated by a facile hydrothermal method. The preparation conditions, such as Ni/Mg molar ratio and hydrothermal reaction time, are evaluated carefully.

2D-2D growth of NiFe LDH nanoflakes on montmorillonite for cationic and anionic dye adsorption performance.

NiFe layered double hydroxides nanoflakes decorated montmorillonite (MMT@NiFe LDH) was successfully prepared by a one-pot hydrothermal method. The 2D-2D growth MMT@NiFe LDH was utilized as an effective adsorbent for removal of anionic dye of methyl orange (MO) and cationic dye of methylene blue (MB). The mole ratio of Ni/Fe could quite influence the interlayer spacing, surface area per unit charge and the ultrathin hexagonal laminated morphology of NiFe LDH decorated on the surface of MMT.