A novel mathematical template for developing fDOM probe fluorescence signal correction models for freshwaters.

The reliable application of field deployable fluorescent dissolved organic matter (fDOM) probes is hindered by several influencing factors which need to be compensated. This manuscript describes the corrections of temperature, pH, turbidity and inner filter effect on fluorescence signal of a commercial fDOM probe (fDOM). For this, Australian waters with wide ranging qualities were selected, e.

Using Surrogate Parameters to Enhance Monitoring of Community Wastewater Management System Performance for Sustainable Operations.

Community wastewater management systems (CWMS) are small-scale wastewater treatment systems typically in regional and rural areas with less sophisticated treatment processes and often managed by local governments or communities. Research and industrial applications have demonstrated that online UV-Vis sensors have great potential for improving wastewater monitoring and treatment processes. Existing studies on the development of surrogate parameters with models from spectral data for wastewater were largely limited to lab-based.

Current trends and future directions of global research on wastewater to energy: a bibliometric analysis and review.

This paper presents a structured bibliometric analysis and review of the research publications recorded in the Web of Science database from 2000 to 2023 to methodically examine the landscape and development of the 'wastewater to energy' research field in relation to global trends, potential hotspots, and future research directions. The study highlights three main research themes in 'wastewater to energy', which are biogas production through anaerobic digestion of sewage sludge, methane generation from microbial wastewater treatment, and hydrogen production from biomass. The analysis reveals activated sludge, biochar, biomethane, biogas upgrading, hydrogen, and circular economy as key topics increasingly gaining momentum in recent research publications as well as representing potential future research directions.

A comprehensive assessment of superabsorbent resin produced using modified quinoa husk and coal fly ash - Preparation, characterization and application.

About 200 million tons of coal fly ash (CFA) is not effectively used in China every year. To enhance the utilization of biomass waste quinoa husk (QH) and solid waste CFA and reduce the preparation cost of superabsorbent resin (SAR), a low-cost, biodegradable modified quinoa husk-g-poly (acrylic acid)/coal fly ash superabsorbent resin (MQH-g-PAA/CFA SAR) was synthesized using modified quinoa husk (MQH), acrylic acid and CFA and used to improve the drought resistance and fertilizer conservation ability of soil. The surface morphology and performance of SAR were characterized by Fourier transform infrared (FTIR) spectrometry, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA), which provided evidence for improving the properties of SAR by grafting MQH and adding CFA.

Microbial Desalination Cell for Sustainable Water Treatment: A Critical Review.

In view of increasing threats arising from the shortage of fresh water, there is an urgent need to propose sustainable technologies for the exploitation of unconventional water sources. As a derivative of microbial fuel cells (MFCs), microbial desalination cell (MDC) has the potential of desalinating saline/brackish water while simultaneously generating electricity, as well as treating wastewater. Therefore, it is worth investigating its practicability as a potential sustainable desalination technology.

Development of a Knowledge Graph for Automatic Job Hazard Analysis: The Schema.

In the current practice, an essential element of safety management systems, Job Hazard Analysis (JHA), is performed manually, relying on the safety personnel's experiential knowledge and observations. This research was conducted to create a new ontology that comprehensively represents the JHA knowledge domain, including the implicit knowledge. Specifically, 115 actual JHA documents and interviews with 18 JHA domain experts were analyzed and used as the source of knowledge for creating a new JHA knowledge base, namely the Job Hazard Analysis Knowledge Graph (JHAKG).

Piezoresistivity and AC Impedance Spectroscopy of Cement-Based Sensors: Basic Concepts, Interpretation, and Perspective.

Cement-based sensors include conductive fillers to achieve a sensing capability based on the piezoresistivity phenomenon, in which the electrical resistivity changes with strain. The microstructural characterisation of cement-based sensors can be obtained using a promising non-destructive technique, such as AC impedance spectroscopy (ACIS), which has been recently used by many researchers. This paper reviews the fundamental concepts of piezoresistivity and ACIS in addition to the comparison of equivalent circuit models of cement-based sensors found in the literature.

Wastewater inflow time series forecasting at low temporal resolution using SARIMA model: a case study in South Australia.

Forecasts of wastewater inflow are considered as a significant component to support the development of a real-time control (RTC) system for a wastewater pumping network and to achieve optimal operations. This paper aims to investigate patterns of the wastewater inflow behaviour and develop a seasonal autoregressive integrated moving average (SARIMA) forecasting model at low temporal resolution (hourly) for a short-term period of 7 days for a real network in South Australia, the Murray Bridge wastewater network/wastewater treatment plant (WWTP). Historical wastewater inflow data collected for a 32-month period (May 2016 to December 2018) was pre-processed (transformed into an hourly dataset) and then separated into two parts for training (80%) and testing (20%).

Applications of Online UV-Vis Spectrophotometer for Drinking Water Quality Monitoring and Process Control: A Review.

Water quality monitoring is an essential component of water quality management for water utilities for managing the drinking water supply. Online UV-Vis spectrophotometers are becoming popular choices for online water quality monitoring and process control, as they are reagent free, do not require sample pre-treatments and can provide continuous measurements. The advantages of the online UV-Vis sensors are that they can capture events and allow quicker responses to water quality changes compared to conventional water quality monitoring.

Review of Nitrification Monitoring and Control Strategies in Drinking Water System.

Nitrification is a major challenge in chloraminated drinking water systems, resulting in undesirable loss of disinfectant residual. Consequently, heterotrophic bacteria growth is increased, which adversely affects the water quality, causing taste, odour, and health issues. Regular monitoring of various water quality parameters at susceptible areas of the water distribution system (WDS) helps to detect nitrification at an earlier stage and allows sufficient time to take corrective actions to control it.

Development of an Optical Method to Monitor Nitrification in Drinking Water.

Nitrification is a common issue observed in chloraminated drinking water distribution systems, resulting in the undesirable loss of monochloramine (NHCl) residual. The decay of monochloramine releases ammonia (NH), which is converted to nitrite (NO) and nitrate (NO) through a biological oxidation process. During the course of monochloramine decay and the production of nitrite and nitrate, the spectral fingerprint is observed to change within the wavelength region sensitive to these species.

Innovative method of utilising hydrogen peroxide for source water management of cyanobacteria.

The treatment and control of cyanobacterial blooms using copper-based algaecides in water reservoirs have historically been used; however, due to the adverse impact of copper on the environment, water authorities have been researching and studying new and innovative ways to control cyanobacterial blooms. Hydrogen peroxide has been investigated as an environmentally friendly alternative, and this research aims to determine the impact of water quality on its effectiveness based on the decay characteristics in different water samples. Natural water samples from South Australian reservoirs and river were used to evaluate hydrogen peroxide decomposition and provide a better strategy for water operators in using it as an algaecide.

Stormwater monitoring using on-line UV-Vis spectroscopy.

Stormwater runoff contains a myriad of pollutants, including faecal microbes, and can pose a threat to urban water supplies, impacting both economic development and public health. Therefore, it is a necessity to implement a real-time hazard detection system that can collect a substantial amount of data, assisting water authorities to develop preventive strategies to ensure the control of hazards entering drinking water sources. An on-line UV-Vis spectrophotometer was applied in the field to collect real-time continuous data for various water quality parameters (nitrate, DOC, turbidity and total suspended solids) during three storm events in Mannum, Adelaide, Australia.

Spectrophotometric Online Detection of Drinking Water Disinfectant: A Machine Learning Approach.

The spectra fingerprint of drinking water from a water treatment plant (WTP) is characterised by a number of light-absorbing substances, including organic, nitrate, disinfectant, and particle or turbidity. Detection of disinfectant (monochloramine) can be better achieved by separating its spectra from the combined spectra. In this paper, two major focuses are (i) the separation of monochloramine spectra from the combined spectra and (ii) assessment of the application of the machine learning algorithm in real-time detection of monochloramine.

Evaluation of the impact of suspended particles on the UV absorbance at 254 nm (UV) measurements using a submersible UV-Vis spectrophotometer.

There is an increasing need to use online instrumentation for continuous monitoring of water quality. However, industrial applications using online instruments, such as submersible UV-Vis spectrophotometers, may require the use of alternative techniques to remove particle effect rather than performing a physical filtration step. Some submersible UV-Vis spectrophotometers have built-in generic particle compensation algorithms to remove the filtration step.

Durability of Fibre-Reinforced Calcium Aluminate Cement (CAC)-Ground Granulated Blast Furnace Slag (GGBFS) Blended Mortar after Sulfuric Acid Attack.

Concrete wastewater infrastructures are important to modern society but are susceptible to sulfuric acid attack when exposed to an aggressive environment. Fibre-reinforced mortar has been adopted as a promising coating and lining material for degraded reinforced concrete structures due to its unique crack control and excellent anti-corrosion ability. This paper aims to evaluate the performance of polyethylene (PE) fibre-reinforced calcium aluminate cement (CAC)-ground granulated blast furnace slag (GGBFS) blended strain-hardening mortar after sulfuric acid immersion, which represented the aggressive sewer environment.

Recycling drinking water treatment sludge into eco-concrete blocks with CO curing: Durability and leachability.

Drinking water treatment sludge (DWTS) can be recycled into low-strength concrete blocks for construction use. The sodium sulfate resistance and leaching behaviours of the DWTS-derived blocks are investigated in this study. The experimental results show that the addition of DWTS degrades the sodium sulfate resistance of the concrete blocks, however CO curing compensates for such property, especially in the case of blocks incorporating 30% DWTS.

Utilization of drinking water treatment sludge in concrete paving blocks: Microstructural analysis, durability and leaching properties.

The management of abundant drinking water treatment sludge (DWTS) in landfill remains an important issue. The reuse of DWTS as construction material could contribute to the development of greener concrete product and to mitigating the detrimental environment effect from excessive production of DWTS. This paper investigates the potential of using DWTS as sand replacement in Concrete Paving Blocks (CPB).

The key factors and removal mechanisms of sulfadimethoxazole and oxytetracycline by coagulation.

The effects of coagulant dosage, alkalinity, turbidity, ionic strength, and dissolved organic matter (DOM) on the removal of sulfadimethoxazole (SMZ) and oxytetracycline (OTC) by coagulation were studied and the reaction mechanisms of the coagulation process were revealed in this research. From our results, alkalinity, turbidity, ionic strength, and DOM had different effects on the removal of antibiotics. The SMZ and OTC removals were improved with increase in poly-aluminum chloride (PACl) dosage, whereas the turbidity had less influence on the removal of SMZ and OTC because the adsorption of SMZ and OTC to kaolin was low, confirmed by a control when no PACl added.

The development and evaluation of a microstill with conductance detection for low level ammonia monitoring in chloraminated water.

Monitoring low levels of ammonia in chloraminated water can be challenging but is important for effectively managing potable water disinfection. The lower the concentration of free ammonia that can be determined, the tighter the control at the disinfection point, which supports better maintenance of chloramine residuals in the distribution system. In this study a micro-distillation technique was used to selectively separate ammonia into a boric acid solution allowing determination by conductance (i.

Influence of coagulation mechanisms and floc formation on filterability.

Minimizing particles in water is a key goal for improving drinking water quality and safety. The media filtration process, as the last step of the solid-liquid separation process, is largely influenced by the characteristics of flocs, which are formed and controlled within the coagulation process. In a laboratory-based study, the impacts of the physical characteristics of flocs formed using aluminum sulfate on the filtration treatment of two comparative water samples were investigated using a photometric dispersion analyzer and a filterability apparatus.

Developing a chloramine decay index to understand nitrification: A case study of two chloraminated drinking water distribution systems.

The management of chloramine decay and the prevention of nitrification are some of the critical issues faced by water utilities that use chloramine as a disinfectant. In this study, potential association between high performance size exclusion chromatography (HPSEC) data obtained with multiple wavelength Ultraviolet (UV) detection from two drinking water distribution systems in Australia and nitrification occurrence was investigated. An increase in the absorbance signal of HPSEC profiles with UV detection at λ=230nm between apparent molecular weights of 200 to 1000Da was observed at sampling sites that experienced rapid chloramine decay and nitrification while its absorbance signal at λ=254nm decreased.

Chloramine demand estimation using surrogate chemical and microbiological parameters.

A model is developed to enable estimation of chloramine demand in full scale drinking water supplies based on chemical and microbiological factors that affect chloramine decay rate via nonlinear regression analysis method. The model is based on organic character (specific ultraviolet absorbance (SUVA)) of the water samples and a laboratory measure of the microbiological (F) decay of chloramine. The applicability of the model for estimation of chloramine residual (and hence chloramine demand) was tested on several waters from different water treatment plants in Australia through statistical test analysis between the experimental and predicted data.

Seasonal variation in the nature of DOM in a river and drinking water reservoir of a closed catchment.

Dissolved organic matter (DOM) in surface waters used for drinking purposes can vary markedly in character depending on its source within catchments and the timing and intensity of rainfall events. Here we report the findings of a study on the character and concentration of DOM in waters collected during different seasons from Myponga River and Reservoir, South Australia. The character of DOM was assessed in terms of its treatability by enhanced coagulation and potential for disinfection by-product i.

High-performance size exclusion chromatography with a multi-wavelength absorbance detector study on dissolved organic matter characterisation along a water distribution system.

This study examined the associations between dissolved organic matter (DOM) characteristics and potential nitrification occurrence in the presence of chloramine along a drinking water distribution system. High-performance size exclusion chromatography (HPSEC) coupled with a multiple wavelength detector (200-280nm) was employed to characterise DOM by molecular weight distribution, bacterial activity was analysed using flow cytometry, and a package of simple analytical tools, such as dissolved organic carbon, absorbance at 254nm, nitrate, nitrite, ammonia and total disinfectant residual were also applied and their applicability to indicate water quality changes in distribution systems were also evaluated. Results showed that multi-wavelength HPSEC analysis was useful to provide information about DOM character while changes in molecule weight profiles at wavelengths less than 230nm were also able to be related to other water quality parameters.