One-Step Conversion of Potassium Organotrifluoroborates to Metal Organoborohydrides.

This letter describes the one-step conversion of heteroatom-substituted potassium organotrifluoroborates (KRBF) to metal monoorganoborohydrides (MRBH) using alkali metal aluminum hydrides. The method tolerates a variety of functional groups, expanding MRBH diversity. Hydride removal with MeSiCl in the presence of dimethylaminopyridine (DMAP) affords the organoborane·DMAP (RBH·DMAP) adducts.

Crystal structure of triphenylphosphonium-meth-yl-enetrifluoroborate.

The title compound, CHBFP {alternative name: triphen-yl[(tri-fluoro-boran-yl)meth-yl]phosphanium}, was formed by the reaction of tri-phenyl-phosphine with potassium iodo-methyl-tri-fluoro-borate. The mol-ecule features a nearly staggered conformation along the P-C bond and a less than staggered conformation along the C-B bond. In the crystal, weak C-H⋯F hydrogen bonds between the -phenyl C-H groups and the tri-fluoro-borate B-F groups form chains of (16) rings along [100].