Experimental Investigation of the Thermal Emission Cross Section of Nanoresonators Using Hierarchical Poisson-Disk Distributions.

Effective cross sections of nano-objects are fundamental properties that determine their ability to interact with light. However, measuring them for individual resonators directly and quantitatively remains challenging, particularly because of the very low signals involved. Here, we experimentally measure the thermal emission cross section of metal-insulator-metal nanoresonators using a stealthy hyperuniform distribution based on a hierarchical Poisson-disk algorithm.

Over-coupled resonator for broadband surface enhanced infrared absorption (SEIRA).

Detection of molecules is a key issue for many applications. Surface enhanced infrared absorption (SEIRA) uses arrays of resonant nanoantennas with good quality factors which can be used to locally enhance the illumination of molecules. The technique has proved to be an effective tool to detect small amount of material.

Helmholtz Resonator Applied to Nanocrystal-Based Infrared Sensing.

While the integration of nanocrystals as an active medium for optoelectronic devices progresses, light management strategies are becoming required. Over recent years, several photonic structures (plasmons, cavities, mirrors, etc.) have been coupled to nanocrystal films to shape the absorption spectrum, tune the directionality, and so on.

High-efficiency second-harmonic generation in coupled nano Fabry-Perot thin resonators.

In this paper we experimentally demonstrate second-harmonic generation (SHG) enhancement in thin 1D periodic plasmonic nanostructures on GaAs in the infrared spectral range. Due to the properly designed coupling of horizontal Fabry-Perot nanoresonators that occurs inside these structures, the obtained conversion efficiencies go up to the 10 W range. Moreover, we demonstrate that the engineering of the plasmonic nanoantenna dimensions on the same GaAs layer can lead to SHG enhancement for pump wavelengths ranging from 2.

Experimental demonstration of second-harmonic generation in high χ metasurfaces.

Metasurfaces able to concentrate light at various wavelengths are promising for enhancing nonlinear interactions. In this Letter, we experimentally demonstrate infrared second-harmonic generation (SHG) by a multi-resonant nanostructure. A 100 GaAs layer embedded in a metal-insulator-metal waveguide is shown to support various localized resonances.

Dispersion-based intertwined SEIRA and SPR effect detection of 2,4-dinitrotoluene using a plasmonic metasurface.

Surface enhanced infrared absorption (SEIRA) spectroscopy and surface plasmon resonance (SPR) make possible, thanks to plasmonics nanoantennas, the detection of low quantities of biological and chemical materials. Here, we investigate the infrared response of 2,4-dinitrotoluene deposited on various arrays of closely arranged metal-insulator-metal (MIM) resonators and experimentally show how the natural dispersion of the complex refractive index leads to an intertwined combination of SEIRA and SPR effect that can be leveraged to identify molecules. They are shown to be efficient for SEIRA spectroscopy and allows detecting of the dispersive explosive material, 2,4-dinitrotoluene.

Electrodynamic resonance of surface conduction and THz transmission through arrays of rectangular apertures in opaque metallic thin films.

A modal method is developed analytically to investigate the THz optical transmission and reflection of a metallic thin film perforated by a 2D array of rectangular apertures. For subwavelength apertures, this optical model is interpreted in terms of passive electrical circuits, with interface admittances accounting for the THz surface conduction properties of the metallic film. The reactive component of the admittance of the evanescent diffraction cloud is shown to exhibit resonant behavior governed by the shape factors of the array.

Ultrathin Epitaxial Silicon Solar Cells with Inverted Nanopyramid Arrays for Efficient Light Trapping.

Ultrathin c-Si solar cells have the potential to drastically reduce costs by saving raw material while maintaining good efficiencies thanks to the excellent quality of monocrystalline silicon. However, efficient light trapping strategies must be implemented to achieve high short-circuit currents. We report on the fabrication of both planar and patterned ultrathin c-Si solar cells on glass using low temperature (T < 275 °C), low-cost, and scalable techniques.

Peptidic ligands to control the three-dimensional self-assembly of quantum rods in aqueous media.

The use of peptidic ligands is validated as a generic chemical platform allowing one to finely control the organization in solid phase of semiconductor nanorods originally dispersed in an aqueous media. An original method to generate, on a macroscopic scale and with the desired geometry, three-dimensional supracrystals composed of quantum rods is introduced. In a first step, nanorods are transferred in an aqueous phase thanks to the substitution of the original capping layer by peptidic ligands.

Crystallization-induced dynamic resolution of Fox chiral auxiliary and application to the diastereoselective electrophilic fluorination of amide enolates.

A highly efficient crystallization-induced dynamic resolution (CIDR) of trans-Fox (fluorinated oxazolidine) chiral auxiliary is reported. This chiral auxiliary was used for highly diastereoselective (>98% de) electrophilic fluorination of amide enolates. After removal of the chiral auxiliary, highly valuable enantiopure α-fluorocarboxylic acids and β-fluoroalcohols are obtained.

Free-standing guided-mode resonance band-pass filters: from 1D to 2D structures.

We study experimentally and theoretically band-pass filters based on guided-mode resonances in free-standing metal-dielectric structures with subwavelength gratings. A variety of filters are obtained: polarizing filters with 1D gratings, and unpolarized or selective filters with 2D gratings, which are shown to behave as two crossed-1D structures. In either case, a high transmission (up to ≈ 79 %) is demonstrated, which represents an eight-fold enhancement compared to the geometrical transmission of the grating.

Three-dimensional self-assembling of gold nanorods with controlled macroscopic shape and local smectic B order.

We describe a method of controlled evaporation on a textured substrate for self-assembling and shaping gold-nanorod-based materials. Tridimensional wall features are formed over areas as large as several square millimeters. Furthermore, analyses by small-angle X-ray scattering and scanning electron microscopy techniques demonstrate that colloids are locally ordered as a smectic B phase.