Stability of arsenate-bearing Fe(III)/Al(III) co-precipitates in the presence of sulfide as reducing agent under anoxic conditions.

Currently, the co-precipitation of arsenate with ferric iron at molar ratios Fe(III)/As(V) ≥ 3 by lime neutralization produces tailings solids that are stable under oxic conditions. However not much is known about the stability of these hazardous co-precipitates under anoxic conditions. These can develop in tailings storage sites by the action of co-discharged reactive sulfides, organic reagent residuals or bacterial activity.

Stability of continuously produced Fe(II)/Fe(III)/As(V) co-precipitates under periodic exposure to reducing agents.

Arsenic mobilized during ore processing necessitates its effective removal from process effluents and disposal in environmentally stable tailings. The most common method to accomplish this involves co-precipitation with excess ferric iron during lime neutralization. The precipitates produced are stable under oxic conditions.