Kinetics of thermal degradation and lifetime study of poly(vinylidene fluoride) (PVDF) subjected to bioethanol fuel accelerated aging.

PVDF was prepared by compression molding, and its phase content/structure was assessed by WAXD, DSC, and FTIR-ATR spectroscopy. Next, PVDF samples were aged in bioethanol fuel at 60 °C or annealed in the same temperature by 30 ─ 180 days. Then, the influence of aging/annealing on thermal stability, thermal degradation kinetics, and lifetime of the PVDF was investigated by thermogravimetric analysis (TGA/DTG), as well as the structure was again examined.

Sustainable recycling of mooring ropes from decommissioned offshore platforms.

Decommissioning offshore Floating Production, Storage and Offloading (FPSO) platforms requires extensive technical knowledge, since it generates different post-consumer materials, including mooring lines. These ropes are made from polyester high tenacity yarn, based on polyethylene terephthalate (PET), and their high added value means they should not be discarded as scrap. This paper aims to present a review and technical opportunities, from an economic standpoint, of recycling the mooring lines recovered from decommissioned FPSOs.

Data on tensile tests and NMR measurements of poly(vinilidene fluoride) before and after stress relaxation.

Poly(vinilidene fluoride) was characterized before and after stress relaxation by tensile tests and time-domain nuclear magnetic resonance (TD-NMR). Tensile tests were performed to provide mechanical properties, focused on the data of elastic modulus for this matter. The TD-NMR technique was used to calculate the fraction of crystalline, constrained amorphous and free amorphous phase, and the transversal relaxation time of each of these phases.