Photodissociation dynamics of IrBr6(2-) dianions by time-resolved photoelectron spectroscopy.

We have used femtosecond time-resolved photoelectron spectroscopy to examine the photodissociation dynamics of doubly charged anions IrBr(6)(2-) after excitation at h nu(pump) = 1.6 eV and with a detachment photon energy of h nu(probe) = 4.8 eV.