We present the first ab initio calculation of a radiative transition of a hadronic resonance within quantum chromodynamics (QCD). We compute the amplitude for ππ→πγ^{⋆}, as a function of the energy of the ππ pair and the virtuality of the photon, in the kinematic regime where ππ couples strongly to the unstable ρ resonance. This exploratory calculation is performed using a lattice discretization of QCD with quark masses corresponding to m_{π}≈400 MeV.
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