Programmable Interfacial Band Configuration in WS/BiOSe Heterojunctions.

van der Waals heterojunctions based on transition-metal dichalcogenides (TMDs) offer advanced strategies for manipulating light-emitting and light-harvesting behaviors. A crucial factor determining the light-material interaction is in the band alignment at the heterojunction interface, particularly the distinctions between type-I and type-II alignments. However, altering the band alignment from one type to another without changing the constituent materials is exceptionally difficult.

Mechanomaterials and Nanomechanics: Toward Proactive Design of Material Properties and Functionalities.

While conventional mechanics of materials offers a passive understanding of the mechanical properties of materials in existing forms, a paradigm shift, referred to as mechanomaterials, is emerging to enable the proactive programming of materials' properties and functionalities by leveraging force-geometry-property relationships. One of the foundations of this new paradigm is nanomechanics, which permits functional and structural materials to be designed based on principles from the nanoscale and beyond. Although the field of mechanomaterials is still in its infancy at the present time, we discuss the current progress in three specific directions closely linked to nanomechanics and provide perspectives on these research foci by considering the potential research directions, chances for success, and existing research capabilities.

Upcycling fish scales through heating for steganography and Rhodamine B adsorption application.

With increasing population and limited resources, a potential route for improving sustainability is increased reuse of waste materials. By re-looking at wastes, interesting properties and multifunctionalities can be discovered in materials previously explored. Despite years of research on bio-compatible fish scales, there is limited study on the fluorescence property of this abundant waste material.

Dynamic Tuning of Moiré Superlattice Morphology by Laser Modification.

In artificial van der Waals (vdW) layered devices, twisting the stacking angle has emerged as an effective strategy to regulate the electronic phases and optical properties of these systems. Along with the twist registry, the lattice reconstruction arising from vdW interlayer interaction has also inspired significant research interests. The control of twist angles is significantly important because the moiré periodicity determines the electron propagation length on the lattice and the interlayer electron-electron interactions.

Nanopath-Beacons for Directed Silver Dendrites' Migration across Graphene Oxide Terrain.

With their special hierarchical fractal and highly symmetric formation, silver dendrites have a large surface area and plentiful active sites at edges, which have allowed them to exhibit unique properties ranging from superhydrophobic surfaces to biosensors. Yet, many suggested synthesis processes either require a long reaction time or risk contamination from sacrificial elements. Limited research in directing while enhancing the growth of these silver dendrites also hinders the application of these unique microstructures as site-selective hydrophobicity of surfaces and location-dependent SERS (surface-enhanced Raman spectroscopy).

Electrochemically Exfoliated Platinum Dichalcogenide Atomic Layers for High-Performance Air-Stable Infrared Photodetectors.

Platinum dichalcogenide (PtX), an emergent group-10 transition metal dichalcogenide (TMD) has shown great potential in infrared photonic and optoelectronic applications due to its layer-dependent electronic structure with potentially suitable bandgap. However, a scalable synthesis of PtSe and PtTe atomic layers with controlled thickness still represents a major challenge in this field because of the strong interlayer interactions. Herein, we develop a facile cathodic exfoliation approach for the synthesis of solution-processable high-quality PtSe and PtTe atomic layers for high-performance infrared (IR) photodetection.

Heteromoiré Engineering on Magnetic Bloch Transport in Twisted Graphene Superlattices.

Localized electrons subject to applied magnetic fields can restart to propagate freely through the lattice in delocalized magnetic Bloch states (MBSs) when the lattice periodicity is commensurate with the magnetic length. Twisted graphene superlattices with moiré wavelength tunability enable experimental access to the unique delocalization in a controllable fashion. Here, we report the observation and characterization of high-temperature Brown-Zak (BZ) oscillations which come in two types, 1/ and periodicity, originating from the generation of integer and fractional MBSs, in the twisted bilayer and trilayer graphene superlattices, respectively.

Band Nesting Bypass in WS Monolayers Förster Resonance Energy Transfer.

Two-dimensional (2D) transition-metal dichalcogenides (TMDs) have attracted intensive interest due to the direct-band-gap transition in the monolayer form, positioning them as potential next-generation materials for optoelectronic or photonic devices. However, the band-nested suppression of the recombination efficiency at higher excitation energies limits the ability to locally control and manipulate the photoluminescence of WS for multifunctional applications. In this work, we exploit an energy transfer method to modulate the fluorescence properties of TMDs under a larger excitation range spanning from UV to visible light.

Electrically Tailored Metachrosis in ZnO-C Nanowires.

Carbon incorporated zinc oxide (ZnO:C) nanowires (NWs) are found to be remarkable morphing NWs. We show that the physical properties of ZnO:C NWs are engineered the passage of electric current to produce fluorescence differences and negative differential resistance as well as electroluminescence. When a ZnO:C NW is subjected to an applied voltage bias and under ultraviolet (UV) excitation, electron-hole separation due to the voltage biasing suppresses their fluorescence at low voltages.

Fluorescence Invigoration in Carbon-Incorporated Zinc Oxide Nanowires from Passage of Field Emission Electrons.

We demonstrate that carbon incorporated Zinc Oxide (C-ZnO) nanowires (NWs) exhibit remarkable improvement in the extent and quality of fluorescence emission after they are utilized as an electron source in a field emission experiment. After the passage of field emission electrons, the intensity of the fluorescence emitted from these NWs in the visible light range exhibits a 2.5 to 8 fold enhancement.

The Role of Oxygen Atoms on Excitons at the Edges of Monolayer WS.

We clarify that the chemisorption of oxygen atoms at the edges is a key contributor to the frequently observed edge enhancement and spatial non-uniformities of photoluminescence (PL) in WS monolayers. Here we have investigated with momentum- and real-space nanoimaging of the chemical and electronic density inhomogeneity of WS flakes. Our finding from a large panoply of techniques together with density functional theory calculation confirms that the oxygen chemisorption leads to the electron accumulation at the edges.

Nanosurfer flash-mobs: electric-field-choreographed silver migration on graphene oxide.

We report for the first time the ability to direct and control the migration path of silver nanoparticles across graphene oxide (GO). With the help of a focused laser beam, we demonstrated choreographed nanoparticle assembly on GO a directed electric-field. Silver migration and the resultant dendrite formation on GO were characterized through electrical testing coupled with fluorescence microscopy.

One-dimensional nanostructures of II-VI ternary alloys: synthesis, optical properties, and applications.

One-dimensional (1D) nanostructures of II-VI ternary alloys are of prime interest due to their compatible features of both 1D nanostructures and semiconducting alloys. These features can facilitate materials with tunable bandgaps, which are crucial to the performance of photoelectrical devices. Herein, we present a comprehensive review summarizing the recent research progress pertinent to the diverse synthesis, optical fundamentals and applications of 1D nanostructures of II-VI ternary alloys.

Tailoring sample-wide pseudo-magnetic fields on a graphene-black phosphorus heterostructure.

Spatially tailored pseudo-magnetic fields (PMFs) can give rise to pseudo-Landau levels and the valley Hall effect in graphene. At an experimental level, it is highly challenging to create the specific strain texture that can generate PMFs over large areas. Here, we report that superposing graphene on multilayer black phosphorus creates shear-strained superlattices that generate a PMF over an entire graphene-black phosphorus heterostructure with edge size of tens of micrometres.

Laser assisted blending of Ag nanoparticles in an alumina veil: a highly fluorescent hybrid.

We report a functional hybrid made of silver nanoparticles (AgNPs) embedded in an amorphous aluminium oxide (alumina) film. This laser-initiated process allows formation of AgNPs and amorphous alumina in localized regions defined by the scanning laser beam. Due to metal enhanced fluorescence, this hybrid exhibits strong blue fluorescence emission under ultraviolet excitation.

Oxygen Passivation Mediated Tunability of Trion and Excitons in MoS_{2}.

Using wide spectral range in situ spectroscopic ellipsometry with systematic ultrahigh vacuum annealing and in situ exposure to oxygen, we report the complex dielectric function of MoS_{2} isolating the environmental effects and revealing the crucial role of unpassivated and passivated sulphur vacancies. The spectral weights of the A (1.92 eV) and B (2.

ZnO Nano-Rod Devices for Intradermal Delivery and Immunization.

Intradermal delivery of antigens for vaccination is a very attractive approach since the skin provides a rich network of antigen presenting cells, which aid in stimulating an immune response. Numerous intradermal techniques have been developed to enhance penetration across the skin. However, these methods are invasive and/or affect the skin integrity.

Microsteganography on WS Monolayers Tailored by Direct Laser Painting.

We present scanning focused laser beam as a multipurpose tool to engineer the physical and chemical properties of WS microflakes. For monolayers, the laser modification integrates oxygen into the WS microflake, resulting in ∼9 times enhancement in the intensity of the fluorescence emission. This modification does not cause any morphology change, allowing "micro-encryption" of information that is only observable as fluorescence under excitation.

Hybrid Bilayer WSe2 -CH3 NH3 PbI3 Organolead Halide Perovskite as a High-Performance Photodetector.

A high-performance 2D photodetector based on a bilayer structure comprising a WSe2 monolayer and CH3 NH3 PbI3 organolead halide perovskite is reported. High performance is realized by modification of the WSe2 monolayer with laser healing and perovskite functionalization. After modification, the output of the device was three orders of magnitude better than the pristine device; the performance is superior to that of most of the 2D photodetectors based on transition-metal-dichalcogenides (TMDs).

Fluorescence Concentric Triangles: A Case of Chemical Heterogeneity in WS2 Atomic Monolayer.

We report a novel optical property in WS2 monolayer. The monolayer naturally exhibits beautiful in-plane periodical and lateral homojunctions by way of alternate dark and bright band in the fluorescence images of these monolayers. The interface between different fluorescence species within the sample is distinct and sharp.

Ultrahigh photoconductivity of bandgap-graded CdSxSe1-x nanowires probed by terahertz spectroscopy.

Superiorly high photoconductivity is desirable in optoelectronic materials and devices for information transmission and processing. Achieving high photoconductivity via bandgap engineering in a bandgap-graded semiconductor nanowire has been proposed as a potential strategy. In this work, we report the ultrahigh photoconductivity of bandgap-graded CdSxSe1-x nanowires and its detailed analysis by means of ultrafast optical-pump terahertz-probe (OPTP) spectroscopy.