Purpose: Gastric cancer still develops after successful Helicobacter pylori(Hp)eradication. In this study, we aimed to explore the characteristics and risks of mucosal factors.
Methods: A total of 139 early gastric cancers (EGC) diagnosed in 133 patients after successful eradication from January 2016 to December 2021 were retrospectively included in the Hp-eradication EGC group and 170 EGCs diagnosed in 158 patients were included in the Hp-positive EGC group.
Multi-resonance thermal activated delayed fluorescence (MR-TADF) has been promising with large oscillator strength and narrow full width at half maxima of luminescence, overcoming the compromise of emission intensity and energy criteria of traditional charge transfer TADF frameworks. However, there are still limited theoretical investigations on the excitation mechanism and systematic molecular manipulation of MR-TADF structures. We systematically study the highly localized excitation (LE) characteristics based on typical blue boron-nitrogen (BN) MR-TADF emitters and prove the potential triangular core with theoretical approaches.
View Article and Find Full Text PDFPhys Chem Chem Phys
May 2019
Here, we formulate a theoretical transport model for disordered organic semiconductors based on the concept of competitive hopping. We demonstrate theoretically that carriers occupying states with higher energy levels have higher probabilities and higher rates of hopping to the transport energy. This model suggests a temperature (T) dependence of mobility (μ) given by lg(μ) ∝ T-n, where the low carrier density and small energetic disorder limitation of the competitive hopping model gives the non-Arrhenius lg(μ) ∝ T-2 relation, and the high carrier density and large energetic disorder limitation gives the Arrhenius type lg(μ) ∝ T-1 relation.
View Article and Find Full Text PDFRecent research studies on noble-metal-free thermally activated delayed fluorescent (TADF) materials have boosted the efficiencies of organic light-emitting diodes (OLEDs) to unity. However, the short lifespan still hinders their further practical application. Carrier recombination pathways have been reported to have a significant influence on the efficiencies of TADF devices, though their effects on device lifetimes remain rarely studied.
View Article and Find Full Text PDFNumerous efforts have been devoted to boost the efficiency of thermally activated delayed fluorescence (TADF) devices; however, strategies to suppress the device efficiency roll-off are still in urgent need. Here, a general and effective approach to suppress the efficiency roll-off of TADF devices is proposed, that is, utilizing TADF materials as the hosts for TADF emitters. Bearing small singlet-triplet splitting (ΔE) with donor and acceptor units, TADF materials as the hosts possess the potential to achieve matched frontier energy levels with the adjacent transporting layers, facilitating balanced charge injection as well as bipolar charge transport mobilities beneficial to the balanced charges transportation.
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