The effect of ultraviolet (UV) light on structural changes is a significant concern, particularly regarding the weathering and aging effects on microplastics (MPs). This research focused on examining how various UV light wavelengths (UVC, UVB, and UVA) influence the adsorption behavior of aged polyethylene (PE) MPs toward tetracycline (TC). To explore the adsorption mechanism in detail, adsorption kinetics were studied under different UV light wavelengths.
View Article and Find Full Text PDFA novel graphene-bridged MoS/CoO (MCG) nanohybrid was well fabricated by a hydrothermal route. The purpose of valuable and economical S-scheme systems with vigorous interface interactions is pressing to photocatalytic efficiency and efficient utilization. While mighty progress has been created with respect to charge carrier bridges, the charge transferring ability of the facility charge carrier bridges is far from capable owing to lower electrical conductivity.
View Article and Find Full Text PDFEfficient detection of chloramphenicol (CAP) in the environment and food products is crucial for addressing global health and environmental safety concerns. This study presents the development of a cost-effective hybrid electrocatalyst comprising lignocellulosic carbon sheets, graphene oxide, and manganese oxide (LCSs/GO@MnO) for CAP detection using a simple electrochemical sensor fabricated on a glassy carbon electrode (GCE) substrate. The synergistic interaction between LCSs, GO, and MnO enhance the electroactive surface area of GCE, facilitating effective dispersion and electrode modification.
View Article and Find Full Text PDFMicroplastics (MPs) pose a growing threat to coral reef ecosystems worldwide. However, data on MP contamination in coral reefs remain limited, hampering accurate ecological risk assessment. This study investigated MP contamination in coral reefs at South Penghu Marine National Park, analyzing 40 samples from 31 coral species.
View Article and Find Full Text PDFDespite the adsorption of microplastics (MPs), the precise quantification of their concentrating effect on persistent organic pollutants (POPs) remains uncertain. Therefore, in this study, POPs in MPs, POPs in suspended particulate matter (SPM), and dissolved POPs in seawater were distinguished to quantify the enrichment factor (EF) for characterizing the concentrating effects of MPs and SPM on POPs. The results showed that the logarithm of EF (log EF) for POPs in MPs was 5.
View Article and Find Full Text PDFThe objective of this study is to comprehensively characterize persistent organic pollutants (POPs) in seawater at Kaohsiung Harbor, focusing on their concentrations, partitioning behaviors, and profiles in both particle and liquid phases. We analyzed 100 L seawater for each sample, finding total dioxin-like toxicity (PCDD/Fs + PCBs + PBDD/Fs) ranging from 0.00936 to 0.
View Article and Find Full Text PDFVanadium (V) is a hazardous element with widespread environmental presence, particularly in marine environments, due to both natural and industrial sources. This review examines vanadium's impact on marine organisms, highlighting its disruption of metabolic processes in fish, microalgae, and crustaceans, leading to oxidative stress, impaired growth and reproduction. Vanadium accumulation in marine food chains poses risks to higher organisms, including humans.
View Article and Find Full Text PDFThe pervasive issue of microplastics in aquatic environments presents a formidable challenge to traditional water treatment methodologies, including those utilizing KMnO. This study pioneers advanced oxidation processes (AOPs) method aimed at improving the degradation of PE microplastics by employing a dual treatment strategy that combines KMnO oxidation with UV irradiation. Detailed analysis of the surface modifications and chemical functional groups of the treated PE microplastics revealed the establishment of Mn-O-Mn linkages on their surfaces.
View Article and Find Full Text PDFEnviron Geochem Health
September 2024
Microalgae-assisted bioremediation, enriched by nanomaterial integration, offers a sustainable approach to environmental pollution mitigation while harnessing microalgae's potential as a biocatalyst and biorefinery resource. This strategy explores the interaction between microalgae, nanomaterials, and bioremediation, advancing sustainability objectives. The potent combination of microalgae and nanomaterials highlights the biorefinery's promise in effective pollutant removal and valuable algal byproduct production.
View Article and Find Full Text PDFRising concerns about global environmental degradation underscore the pressing need for effective solutions to combat heavy metal pollution. Industries such as semiconductor and steel production discharge vanadium into marine ecosystems, posing significant risks to both marine life and human health. The current study investigates efficacy of utilizing marine thraustochytrid for efficient vanadium removal outcompeting other microbial sources.
View Article and Find Full Text PDFWe evaluated the influence of organic matter in polycyclic aromatic hydrocarbons (PAHs) in port sediments using multiple linear regression (MLR) and prediction models. Total sediment PAHs ranged between 45 and 3230 ng/g dw (average: 557 ± 962 ng/g dw), with PAHs primarily originating from river inputs, confined to areas near the estuaries. Coal/biomaterial combustion and petroleum mainly contribute to the presence of PAHs along estuaries, with medium-high to high ecological risks.
View Article and Find Full Text PDFThis study examined the sediment metal fractions and availability to infer bioaccumulation in marine harbor benthic organisms. Total metals were analyzed using atomic absorption spectrometry and inductively coupled plasma-optical emission spectrometry for chemical fractions and organisms. The results showed similar metal concentrations and distribution driven by rivers and harbor pollution.
View Article and Find Full Text PDFMarine organisms, especially top predators such as sharks, are susceptible to environmental pollutants like microplastics (MPs) and phthalate esters (PAEs), leading to ecosystem risks. Research on contamination in these apex species is, however, still limited. This study investigated MPs and PAEs in multiple shark species (Isurus oxyrinchus, Alopias superciliosus, Alopias pelagicus, Carcharhinus brevipinna, and Sphyrna zygaena) off Taiwan's eastern coast.
View Article and Find Full Text PDFIn this research, the dimensional catalysts of pure g-CN photocatalysts (1D, 2D, and 3D) were investigated for the reduction of the highly toxic/carcinogenic Cr(VI) under visible light irradiation. The catalysts underwent explanation through various surface analysis techniques. According to the BET data, the specific surface area of the 3D catalyst was 1.
View Article and Find Full Text PDFThis study examines the combined effects of polyethylene microplastics (PE-MP) and copper (Cu) on the immune and oxidative response of Litopenaeus vannamei. PE-MP adsorbed with Cu at 2.3, 6.
View Article and Find Full Text PDFThe interest in algae-derived bioactive compounds has grown due to their potential therapeutic efficacy against a range of diseases. These compounds, derived from proteins, exhibit diverse functions and profound pharmacological effects. Recent research has highlighted the extensive health benefits of algae-derived bioactive compounds, positioning them as potential natural antioxidants in the food, pharmaceutical, and cosmetic industries.
View Article and Find Full Text PDFBioactive polysaccharides and oligosaccharides were successfully extracted from three distinct seaweeds: sp., sp., and sp.
View Article and Find Full Text PDFIn the evolving field of food and agriculture, pesticide utilization is inevitable for food production and poses an increasing threat to the ecosystem and human health. This review systematically investigates and provides a comprehensive overview of recent developments in smart electrochemical devices for detecting pesticides in agricultural food and runoff contaminants. The focus encompasses recent progress in lab-scale and portable electrochemical sensors, highlighting their significance in agricultural pesticide monitoring.
View Article and Find Full Text PDFIn this study, biochar derived from chestnut shells was synthesized through pyrolysis at varying temperatures from 300 °C to 900 °C. The study unveiled that the pyrolysis temperature is pivotal in defining the physical and chemical attributes of biochar, notably its adsorption capabilities and its role in activating peracetic acid (PAA) for the efficient removal of acetaminophen (APAP) from aquatic environments. Notably, the biochar processed at 900 °C, referred to as CN900, demonstrated an exceptional adsorption efficiency of 55.
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