In recent years, conversion-based mixed transition-metal oxides have emerged as a potential anode for the next generation lithium-ion batteries because of their high theoretical capacity and high rate performance. Herein, an interconnected cobalt molybdenum oxide (CoMoO) nanoarchitecture derived from molybdenum sulfide (MoS) nanoflowers is investigated as an anode for lithium-ion batteries. The interconnected CoMoO displayed an excellent discharge capacity of 1100 mA h g over 100 cycles at a current rate of C/5.
View Article and Find Full Text PDFThe photocatalytic degradation of methylene blue (MB) dye in aqueous solution was investigated using hexagonal molybdenum oxide (h-MoO3) nanocrystals under visible light irradiation. Chemical precipitation method was utilized to synthesize h-MoO3 and control over the crystal size, shape and distribution were characterized by using HNO3 and HCl as precipitating reagents. The photocatalysts were examined through X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray spectrum (EDX) for structural, functional, surface morphology and elemental analysis, respectively.
View Article and Find Full Text PDFA detailed study on visible light photocatalytic degradation of methylene blue (MB) has been investigated in aqueous heterogeneous media containing hexagonal phase molybdenum oxide (h-MoO3) nanocrystals (NCs) which was identified as a new material for visible light driven photocatalysis. A simple and template-free solution based chemical precipitation method was employed to synthesize h-MoO3 NCs by reacting ammonium heptamolybdate tetrahydrate (AHM) with nitric acid. The formation and growth mechanism of h-MoO3 microstructures was explained.
View Article and Find Full Text PDFHexagonal molybdenum oxide (h-MoO(3)) was synthesized by a solution based chemical precipitation technique. Analysis by X-ray diffraction (XRD) confirmed that the as-synthesized powder had a metastable hexagonal structure. The characteristic vibrational band of Mo-O was identified from Fourier transform infrared spectroscopy (FT-IR).
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