With the aim to resolve the problem of water pollution, we herein propose a new photocatalyst based on metal-organic frameworks (MOFs), called La-doped MIL-88B(Fe)-NH (MIL-88B((1 - )Fe/La)-NH), which was designed and employed for the photocatalytic reduction of Cr(vi) in aqueous solutions. MIL-88B((1-)Fe/La)-NH materials with different values were synthesized a one-pot solvothermal method. Their characteristics were investigated using various techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), Brunauer-Emmett-Teller (BET) analysis, Fourier-transform infrared (FT-IR) spectroscopy and ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS).
View Article and Find Full Text PDFA new graphene oxide (GO) nanocomposite that contains chitosan, a biological polymer, combined with a magnetic nanoparticle inorganic material (FeO) was successfully prepared and applied for the adsorption of Pb(II) from aqueous solutions. The structural and morphological properties of the GO/FeO/CS (GFC) nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Influent factors for Pb(II) adsorption, including the contacting time, pH of the working medium, working temperature, and adsorbent dosage on the adsorption efficiency, have been optimized.
View Article and Find Full Text PDFWe propose here an electrochemical platform for multi-heavy metal ion detection in water based on MIL-88B(Fe)-NH, an amine-functioned metal-organic framework (MOF) for modifying the surface of a glassy carbon electrode (GCE). Herein, MIL-88B(Fe)-NH with abundant functionalized amine groups can play the role of capture sites for the enrichment of metal ions before electrochemical oxidation sensing. MIL-88B(Fe)-NH was synthesized under optimized conditions through a solvothermal method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transition electron microscopy (TEM), Fourier-transform infrared spectroscopy (FT-IR), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques.
View Article and Find Full Text PDFA novel nanostructured electrode material based on electrochemically reduced graphene oxide/polyaniline nanowires/silver nanoflowers (ERGO/PANi NWs/AgNFs) was fabricated site-specifically onto a Pt microelectrode (0.80 mm area) using a three-step electrochemical procedure: electrosynthesis of ERGO, electropolymerization of PANi NWs, and electrodeposition of AgNFs. Synergistic and complementary properties of ERGO, PANi NWs and AgNFs, including high electrochemical activity, large surface area, and high biocompatibility, were obtained.
View Article and Find Full Text PDFNanostructured cathode materials based on Mn-doped olivine LiMnFePO (x = 0, 0.1, 0.2, and 0.
View Article and Find Full Text PDFA method is described for the synthesis of a nanocomposite containing FeOOH and N-doped carbon nanosheets. The nanocomposite was synthesized by a hydrothermal method using a FeO/chitosan nanocomposite as the precursor. The nanocomposite displays peroxidase-like activity and catalyzes the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) by HO.
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