Facile Preparation of Carbon Nanotubes/Cellulose Nanofibrils/Manganese Dioxide Nanowires Electrode for Improved Solid-Sate Supercapacitor Performances.

Wearable energy storage devices require high mechanical stability and high-capacitance flexible electrodes. In this study, we design a flexible supercapacitor electrode consisting of 1-dimensional carbon nanotubes (CNT), cellulose nanofibrils (CNF), and manganese dioxide nanowires (MnO NWs). The flexible and conductive CNT/CNF-MnO NWs suspension was first prepared via ultrasonic dispersion approach, followed by vacuum filtration and hot press to form the composite paper electrode.

Development of Biodegradable Rigid Foams from Pineapple Field Waste.

Pineapple materials sourced from agricultural waste have been employed to process novel bio-degradable rigid composite foams. The matrix for the foam consisted of starch extracted from pineapple stem, known for its high amylose content, while the filler comprised non-fibrous cellulosic materials sourced from pineapple leaf. In contrast to traditional methods that involve preparing a batter, this study adopted a unique approach where the starch gel containing glycerol were first formed using a household microwave oven, followed by blending the filler into the gel using a two-roll mill.

Toward a Circular Bioeconomy: Exploring Pineapple Stem Starch Film as Protective Coating for Fruits and Vegetables.

In order to reduce our dependence on nonrenewable plastics and solve the problem of non-biodegradable plastic waste, there has been much attention paid to the development of biodegradable plastics from natural resources. Starch-based materials have been widely studied and developed for commercial production, primarily from corn and tapioca. However, the use of these starches could generate food security problems.

Toward a Circular Bioeconomy: Development of Pineapple Stem Starch Composite as a Plastic-Sheet Substitute for Single-Use Applications.

Plastic waste poses a significant challenge for the environment, particularly smaller plastic products that are often difficult to recycle or collect. In this study, we developed a fully biodegradable composite material from pineapple field waste that is suitable for small-sized plastic products that are difficult to recycle, such as bread clips. We utilized starch from waste pineapple stems, which is high in amylose content, as the matrix, and added glycerol and calcium carbonate as the plasticizer and filler, respectively, to improve the material's moldability and hardness.

Toward a Circular Bioeconomy: Exploring Pineapple Stem Starch Film as a Plastic Substitute in Single Use Applications.

In this study, biodegradable starch film was developed from pineapple stem waste as a substitute for non-biodegradable petroleum-based films for single-use applications where strength is not too demanding. High amylose starch from a pineapple stem was used as the matrix. Glycerol and citric acid were used as additives to adjust the ductility of the material.

Chitosan-Bead-Encapsulated Polystyrene Sulfonate for Adsorption of Methylene Blue and Regeneration Studies: Batch and Continuous Approaches.

Textile industrialization causes water pollution due to the discharge of industrial effluents into the environment. To reduce the impact of industrial effluent, it must be treated in wastewater treatment plants before discharge into rivers. Among all wastewater treatment approaches, the adsorption process is one method to remove pollutants from wastewater, but it has some limitations in term of reusability and ionic selective adsorption properties.

Chitosan Nanoparticles as Potential Nano-Sorbent for Removal of Toxic Environmental Pollutants.

Adsorption is the most widely used technique for advanced wastewater treatment. The preparation and application of natural renewable and environmentally friendly materials makes this process easier and more profitable. Chitosan is often used as an effective biomaterial in the adsorption world because of its numerous functional applications.

Chitosan Fibers Loaded with Limonite as a Catalyst for the Decolorization of Methylene Blue via a Persulfate-Based Advanced Oxidation Process.

Wastewater generated from industries seriously impacts the environment. Conventional biological and physiochemical treatment methods for wastewater containing organic molecules have some limitations. Therefore, identifying other alternative methods or processes that are more suitable to degrade organic molecules and lower chemical oxygen demand (COD) in wastewater is necessary.

Biogenic Synthesis of Copper-Based Nanomaterials Using Plant Extracts and Their Applications: Current and Future Directions.

Plants have been used for multiple purposes over thousands of years in various applications such as traditional Chinese medicine and Ayurveda. More recently, the special properties of phytochemicals within plant extracts have spurred researchers to pursue interdisciplinary studies uniting nanotechnology and biotechnology. Plant-mediated green synthesis of nanomaterials utilises the phytochemicals in plant extracts to produce nanomaterials.

Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator.

In this study, a cellulose membrane (CM) was chemically treated with phenolic (PF) resin to improve its performance as a polymeric insulator. The CM was prepared from kenaf pulp, and the PF was synthesized from oil palm empty fruit (EFB) fibre. Four different concentrations of synthesized PF resin (5, 10, 15, and 20 wt.

Recent advancement in 3-D printing: nanocomposites with added functionality.

Three-Dimentional (3-D) printing is currently a popular printing technique that is used in many sectors. Potentially, this technology is expected to replace conventional manufacturing in the coming years. It is accelerating in gaining attention due to its design freedom where objects can be produced without imagination boundaries.

Production of Rigid Polyurethane Foams Using Polyol from Liquefied Oil Palm Biomass: Variation of Isocyanate Indexes.

Development of polyurethane foam (PUF) containing bio-based components is a complex process that requires extensive studies. This work reports on the production of rigid PUFs from polyol obtained via liquefaction of oil palm empty fruit bunch (EFB) biomass with different isocyanate (NCO) indexes. The effect of the NCO index on the physical, chemical and compressive properties of the liquefied EFB-based PUF (EFBPUF) was evaluated.

Seventeen-Armed Star Polystyrenes in Various Molecular Weights: Structural Details and Chain Characteristics.

Star-shaped polymers are very attractive because of their potential application ability in various technological areas due to their unique molecular topology. Thus, information on the molecular structure and chain characteristics of star polymers is essential for gaining insights into their properties and finding better applications. In this study, we report molecular structure details and chain characteristics of 17-armed polystyrenes in various molecular weights: 17-Arm(2k)-PS, 17-Arm(6k)-PS, 17-Arm(10k)-PS, and 17-Arm(20k)-PS.

Copper Nanowires as Highly Efficient and Recyclable Catalyst for Rapid Hydrogen Generation from Hydrolysis of Sodium Borohydride.

Hydrogen (H) is a clean energy carrier which can help to solve environmental issues with the depletion of fossil fuels. Sodium borohydride (NaBH) is a promising candidate material for solid state hydrogen storage due to its huge hydrogen storage capacity and nontoxicity. However, the hydrolysis of NaBH usually requires expensive noble metal catalysts for a high H generation rate (HGR).

Quantitative Structural Analysis of Polystyrene Nanoparticles Using Synchrotron X-Ray Scattering and Dynamic Light Scattering.

A series of polystyrene nanoparticles (PS-1, PS-2, PS-3, and PS-4) in aqueous solutions were investigated in terms of morphological structure, size, and size distribution. Synchrotron small-angle X-ray scattering analysis (SAXS) was carried out, providing morphology details, size and size distribution on the particles. PS-1, PS-2, and PS-3 were confirmed to behave two-phase (core and shell) spherical shapes, whereas PS-4 exhibited a single-phase spherical shape.

Telescopic synthesis of cellulose nanofibrils with a stable dispersion of Fe(0) nanoparticles for synergistic removal of 5-fluorouracil.

The recognition of cellulose nanofibrils (CNF) in the past years as a high prospect material has been prominent, but the impractical cellulose extraction method from biomass remained as a technological barrier for industrial practice. In this study, the telescopic approach on the fractionation of lignin and cellulose was performed by organosolv extraction and catalytic oxidation from oil palm empty fruit bunch fibers. The integration of these techniques managed to synthesize CNF in a short time.

Rapid Catalytic Reduction of 4-Nitrophenol and Clock Reaction of Methylene Blue using Copper Nanowires.

Copper nanowires (CuNWs) with a high aspect ratio of ~2600 have been successfully synthesized by using a facile hydrothermal method. The reductions of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) and methylene blue (MB) to leucomethylene blue (LMB) by using sodium borohydride (NaBH) were used as models to test the catalytic activity of CuNWs. We showed that by increasing the CuNWs content, the rate of reduction increased as well.

Highly stable binder free CNTs/rGO aerogel electrode for decolouration of methylene blue & palm oil mill effluent electro-Fenton oxidation process.

In this study, single wall carbon nanotubes (CNTs)/reduced graphene oxides (rGO) aerogels were prepared by a one-pot hydrothermal process without using a binder. The produced CNTs/rGO aerogel was used as cathode in electro-Fenton system for the decolouration of methylene blue (MB) and palm oil mill effluent (POME). The addition of CNTs increased the surface area, pore volume and conductivity of the rGO aerogel, which further enhanced their performance as cathode towards the decolouration of MB and POME electro-Fenton reaction.

Chemically crosslinked hydrogel and its driving force towards superabsorbent behaviour.

Dissolved oil palm empty fruit bunch (EFB) cellulose in NaOH/urea solvent was mixed with sodium carboxymethylcellulose (NaCMC) to form a green regenerated superabsorbent hydrogel. The effect of concentration of epichlorohydrin (ECH) as the crosslinker on the formation, physical, and chemical properties of hydrogel was studied. Rapid formation and higher gel content of hydrogel were observed at 10% concentration of ECH.

Highly porous regenerated cellulose hydrogel and aerogel prepared from hydrothermal synthesized cellulose carbamate.

Here, a stable derivative of cellulose, called cellulose carbamate (CC), was produced from Kenaf (Hibiscus cannabinus) core pulp (KCP) and urea with the aid of a hydrothermal method. Further investigation was carried out for the amount of nitrogen yielded in CC as different urea concentrations were applied to react with cellulose. The effect of nitrogen concentration of CC on its solubility in a urea-alkaline system was also studied.

Synthesis of kenaf cellulose carbamate and its smart electric stimuli-response.

Cellulose carbamate (CC) was produced from kenaf core pulp (KCP) via a microwave reactor-assisted method. The formation of CC was confirmed by Fourier transform infrared spectroscopy and nitrogen content analysis. The degree of substitution, zeta potential and size distribution of CC were also determined.

Effect of acid hydrolysis on regenerated kenaf core membrane produced using aqueous alkaline-urea systems.

Bleached kenaf core pulps (BKC) were hydrolyzed in H2SO4 (0.5M) at different time (0min to 90min) at room temperature. After the hydrolysis process, the viscosity average molecular weight (Mŋ) for BKC sample has reduced from 14.

Exceedingly biocompatible and thin-layered reduced graphene oxide nanosheets using an eco-friendly mushroom extract strategy.

Purpose: A simple, one-pot strategy was used to synthesize reduced graphene oxide (RGO) nanosheets by utilizing an easily available over-the-counter medicinal and edible mushroom, Ganoderma lucidum.

Methods: The mushroom was boiled in hot water to liberate the polysaccharides, the extract of which was then used directly for the reduction of graphene oxide. The abundance of polysaccharides present in the mushroom serves as a good reducing agent.

Effect of hydrothermal pretreatment on solubility and formation of kenaf cellulose membrane and hydrogel.

The hydrothermal pretreatment on kenaf core pulp (KCP) was carried out using an autoclave heated in a oil bath at 140°C for 0.5/1/3/5h. The hydrothermal pretreated kenaf (HPK) was dissolved in a LiOH/urea aqueous solution and subsequently used to produce cellulose membrane and hydrogel.