One-Pot Synthesis of Bis(arylamino)pentiptycenes by TiCl-DABCO Assisted Reductive Amination of Pentiptycene Quinone.

The previously eight-step synthesis of bis(arylamino)pentiptycenes () from pentiptycene quinone () can now be achieved in a single step with 18-90% yields through TiCl-DABCO assisted reductive amination with anilines. Both the dual amination of and the reduction of quinone diimines are unprecedented. The π system of can be further expanded, including the formation of bis(diarylamino)pentiptycenes.