Photochromism and photoswitchable luminescence in a Zn cluster-based metal-organic framework with an organic guest.

Photochromic materials coupled with photoswitchable luminescence functionalities are of particular interest due to their potential applications in switches and optical memory devices. However, the construction of such materials, especially those with two-color emission states, is still challenging. In this context, a rare Zn cluster-based host-guest MOF material, (bbmp)[Zn(IPA)(OH)(HO)] (1) (HIPA = isophthalic acid, bbmp·2I = 4,4'-([1,1'-biphenyl]-4,4'-diyl)bis(1-methylpyridin-1-ium) diiodide), was prepared by encapsulating an organic cation into an anionic MOF produced from zinc cations and isophthalic acid ligands, which exhibits reversible naked detectable photochromic properties varying from yellow to green upon UV-Vis light irradiation.