Publications by authors named "Chi-Hwe Tsai"
Article Synopsis
- The self-assembly of AgClO(4) with different Schiff-base ligands resulted in two distinct structures: a 1D zigzag polymeric array (3) and a discrete molecular rectangle (4).
- Both structures were characterized using single-crystal X-ray diffraction, revealing unique coordination geometries: 3 features Ag(I) in a distorted tetrahedral arrangement, while 4 exhibits a distorted square-planar coordination.
- Complex 3 is unstable in solution and can degrade into a grid architecture (3g), while 4 maintains its integrity in solution and both complexes display unusual red-shifted luminescence behavior at room temperature.
