Quantifying sodium hypochlorite content in hypochlorite-based disinfectants via phase-conversion headspace technique.

In this work, a novel and efficient approach for sodium hypochlorite analysis is proposed via phase-conversion headspace technique, which is based on the gas chromatography (GC) detection of generated carbon dioxide (CO) from the redox reaction of sodium hypochlorite with sodium oxalate. The data obtained by the proposed method suggest the high detecting precision and accuracy. In addition, the method has low detection limits (limit of quantification (LOQ) = 0.

Donor-acceptor moiety functionalized covalent organic frameworks for boosting charge separation and H photogeneration.

Covalent organic frameworks (COFs) have a broad prospect to be used as a photocatalytic platform to convert solar energy into valuable chemicals due to their tunable structures and rich active catalytic sites. However, constructing COFs with tuned sp-carbon donor-acceptor moiety remains an enormous challenge. Herein, we synthesized two new fully π-conjugated cyano-ethylene-linked COFs containing benzotrithiophene as functional group by Knoevenagel polycondensation reaction.

Investigating the potential of structurally defective UiO-66 for Sb (V) removal from tailing wastewater.

Antimony contamination of tailings from the mining process remain attracted a great amount of concern. In this study, defective UiO-66-X crystal materials are rationally constructed using trifluoroacetic acid and hydrochloric acid as modulators for the removal of Sb(V) from actual tailing sand leachates. XRD and TG characterizations reveal that the number and kind of defects in UiO-66 are influenced by the type of modulators and the addition of trifluoroacetic acid makes UiO-66-TFA contain both cluster and ligand defects.

A critical review on adsorption and recovery of fluoride from wastewater by metal-based adsorbents.

Rapid industrialization is deteriorating water quality, and fluoride pollution in water is one of the most serious environmental pollution problems. Adsorption technology is an efficient and selective process for removing fluoride from aqueous solutions using adsorbents. Metal-based adsorbents synergize the advantages of fast adsorption, high adsorption capacity, and excellent selectivity to effectively remove fluoride from water bodies, promising to satisfy environmental sustainability requirements.

Experimental Study of Salicylic Acid as a Calcium Sulfate Dihydrate Scale Inhibitor, Analyzed from Surface Properties and Crystal Growth.

Static and dynamic experiments were carried out to study the antiscale performance of salicylic acid (SA) to calcium sulfate dihydrate (CSD) scale. The CSD scale formed in the reuse of processing of wastewater of phosphorite flotation. The scale surface physicochemical properties have been investigated by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), ζ potential, and contact angle measurements.

Numerical study on supercontinuum generation by different optical modes in AsSe-AsS chalcogenide microstructured fiber.

We investigate supercontinuum generation (SCG) in AsSe-AsS chalcogenide microstructured optical fibers (MOFs) pumped by different optical modes. The influence on SCG by different optical modes including the fundamental and high-order modes is analyzed numerically. The evolution of the supercontinuum (SC) is investigated by changing the pump wavelength (2120, 2580, and 3280 nm) and peak power (from 200 to 1000 W) of each optical mode (LP,LP,LP) in the MOFs with different fiber lengths.

Theoretical investigation on mid-infrared cascaded Raman fiber laser based on tellurite fiber.

A numerical simulation of third-order cascaded Raman fiber laser based on tellurite fiber at the 2-5 μm waveband is presented. The Raman fiber laser can be optimized with the most suitable tellurite fiber length of 0.5-1.