Improved Electrochemical Performance of Spinel LiNiMnO Cathode Materials with a Dual Structure Triggered by LiF at Low Calcination Temperature.

High-voltage spinel LiNiMnO (LNMO), which has the advantages of high energy density, low cost, environmental friendliness, and being cobalt-free, is considered one of the most promising cathode materials for the next generation of power lithium-ion batteries. However, the side reaction at the interface between the LNMO cathode material and electrolyte usually causes a low specific capacity, poor rate, and poor cycling performance. In this work, we propose a facilitated method to build a well-tuned dual structure of LiF coating and F doping LNMO cathode material via simple calcination of LNMO with LiF at low temperatures.

Local field correction to ionization potential depression of ions in warm or hot dense matter.

An analytical self-consistent approach was recently established to predict the ionization potential depression (IPD) in multicomponent dense plasmas, which is achieved by considering the self-energy of ions and electrons within the quantum statistical theory. In order to explicitly account for the exchange-correlation effect of electrons, we incorporate the effective static approximation of local field correction (LFC) within our IPD framework through the connection of dynamical structure factor. The effective static approximation poses an accurate description for the asymptotic large wave number behavior with the recently developed machine learning representation of static LFC induced from the path-integral Monte Carlo data.

Ionization potential depression and Pauli blocking in degenerate plasmas at extreme densities.

New facilities explore warm dense matter (WDM) at conditions with extreme densities (exceeding ten times condensed matter densities) so that electrons are degenerate even at temperatures of 10-100 eV. Whereas in the nondegenerate region correlation effects such as Debye screening are relevant for the ionization potential depression (IPD), new effects have to be considered in degenerate plasmas. In addition to the Fock shift of the self-energies, the bound-state Pauli blocking becomes important with increasing density.

Ionization-potential depression and dynamical structure factor in dense plasmas.

The properties of a bound electron system immersed in a plasma environment are strongly modified by the surrounding plasma. The modification of an essential quantity, the ionization energy, is described by the electronic and ionic self-energies, including dynamical screening within the framework of the quantum statistical theory. Introducing the ionic dynamical structure factor as the indicator for the ionic microfield, we demonstrate that ionic correlations and fluctuations play a critical role in determining the ionization potential depression.