Scalable Fabrication of an MXene/Cotton/Spandex Yarn for Intelligent Wearable Applications.

Wearable sensors based on MXene have attracted attention, but the large-scale production of MXene-based textile materials is still a huge challenge. Hereby, we report a facile way of incorporating MXene into the traditional yarn manufacturing process by dipping and drying MXene into cotton rovings followed by fabricating an MXene/cotton/spandex yarn (MCSY) using friction spinning. The MXene in the MCSY brings electrical conductivity to the MCSY with well-preserved mechanical properties.

Renewable plant-derived lignin for electrochemical energy systems.

Lignin, as one of the most abundant natural polymers, has been proved to be a promising material for the construction of high-performance electrochemical energy systems, including electrodes, electrolytes, and separators, because of their low-cost and sustainable natures and unique structure with abundant functional group. In this review article, we outline some key contributions in this field such as fundamental principles and various electrochemical energy systems including rechargeable batteries, supercapacitors, solar cells, and fuel cells. At the same time, we also point out the significant scientific discussion and critical barriers for lignin-based materials for electrochemical energy systems and also provides feasible strategies for preparing new sustainable energy materials.

One-pot mechanochemical exfoliation of graphite and polymerization of aniline for the production of graphene/polyaniline composites for high-performance supercapacitors.

Graphene/polyaniline composites have attracted considerable attention as high-performance supercapacitor electrode materials; however, there are still numerous challenges for their practical applications, such as the complex preparation process, high cost, and disequilibrium between energy density and power density. Herein, we report an efficient method to produce graphene/polyaniline composites a one-pot ball-milling process, in which aniline molecules act as both the intercalator for the exfoliation of graphite and the monomer for mechanochemical polymerization into polyaniline clusters on the exfoliated graphene sheets. The graphene/polyaniline composite electrode delivered a large specific capacitance of 886 F g at 5 mV s with a high retention of 73.

Cellulose-based Ni-decorated graphene magnetic film for electromagnetic interference shielding.

Flexible and ultrathin electromagnetic interference (EMI) shielding films are urgently required to manage increasingly serious radiation pollution. In this work, the EMI shielding performance and flexibility of conductive polymer films were addressed by assembling magnetic graphene-based hybrid and cellulose nanofiber (CNF). Briefly, magnetic graphene hybrid anchored by Ni nanoparticles (TRGO@Ni) was synthesized by in situ thermal reduction.

Homogeneous coating of carbon nanotubes with tailored N-doped carbon layers for improved electrochemical energy storage.

The combination of activity-enriched heteroatoms and highly-conductive networks is a powerful strategy to craft carbon-based electrodes for high-efficiency electrochemical energy storage. Herein, N-doped carbon (N-C) coated carbon nanotubes (N-CNTs) were fabricated a facile synthesis of polyimide in the presence of carbon nanotubes (CNTs), followed by carbonization. The polyimide-divided N-C layers were uniformly covered on the surface of CNTs with a tailored layer thickness.

In situ encapsulation of CoO polyhedra in graphene sheets for high-capacitance supercapacitors.

Co3O4 polyhedra were well encapsulated in reduced graphene oxide (rGO) sheets by in situ growth of Co-based zeolitic imidazolate framework (ZIF-67) polyhedra in the presence of graphene oxide followed by thermal annealing. The resultant rGO/Co3O4 composites consist of a continuously-conductive double-network constructed from graphene sheets and the derived N-doped carbons from ZIF-67, showing a large specific surface area of 523 m2 g-1. The as-fabricated symmetrical supercapacitor based on rGO/Co3O4 exhibits a high specific capacitance of 277.

Superior flame retardancy and smoke suppression of epoxy-based composites with phosphorus/nitrogen co-doped graphene.

Phosphorus and/or nitrogen doping is an effective method of improving the physical and chemical properties of reduced graphene oxide (rGO). In this work, phosphorus and nitrogen co-doped rGO (PN-rGO), synthesized using a scalable hydrothermal and microwave process, was used as an additive to improve the flame retardancy of epoxy resin (EP) for the first time. Chemical structure and morphology characterization confirmed that the nitrogen and phosphorus atoms were doped into the graphite lattice adopting pyrrolic-N, pyridinic-N, quaternary-N and pyrophosphate and metaphosphate forms.

Graphene-Enabled Superior and Tunable Photomechanical Actuation in Liquid Crystalline Elastomer Nanocomposites.

Programmable photoactuation enabled by graphene: Graphene sheets aligned in liquid crystalline elastomers are capable of absorbing near-infrared light. They thereafter act as nanoheaters and provide thermally conductive pathways to trigger the nematic-to-isotropic transition of elastomers, leading to macroscopic mechanical deformation of nanocomposites. Large strain, high actuation force, high initial sensitivity, fast reversible response, and long cyclability are concurrently achieved in nanocomposites.

Incorporation of liquid-like multiwalled carbon nanotubes into an epoxy matrix by solvent-free processing.

Covalent attachment of 2,2'-(ethylenedioxy)-diethylamine to multiwalled carbon nanotubes (MWCNTs) produced amino-functionalized MWCNTs which behaved like liquids at ambient temperature. These liquid-like MWCNTs (l-MWCNTs) could be homogeneously dispersed and chemically embedded in an epoxy matrix by solvent-free processing. In contrast, solid MWCNTs (s-MWCNTs) functionalized by 1,8-diaminooctane were poorly dispersed in epoxy although they possess chemical structures and functionalization comparable to l-MWCNTs.