Li-N batteries present a relatively novel approach to N immobilization, and an advanced N/LiN cycling method is introduced in this study. The low operating overpotential of metal-air batteries is quite favorable to their stable cycling performance, providing a prospect for the development of a new type of battery with extreme voltage. The battery system of Li-N uses N as the positive electrode, lithium metal as the negative electrode, and a conductive medium containing soluble lithium salts as the electrolyte.
View Article and Find Full Text PDFLithium-sulfur batteries (LSBs) are considered as the development direction of the new generation energy storage system due to their high energy density and low cost. The slow redox kinetics of sulfur and the shuttle effect of lithium polysulfide (LiPS) are considered to be the main obstacles to the practical application of LSBs. Transition-metal sulfide as the cathode host can improve the Li-S redox chemistry.
View Article and Find Full Text PDFLithium-sulfur batteries (LSBs) are one of the most promising energy storage devices with high energy density. However, their application and commercialization are hampered by the slow Li-S redox chemistry. FeMS (M = Ti, V), as the sulfur cathode host, enhances the Li-S redox chemistry.
View Article and Find Full Text PDFPhys Chem Chem Phys
March 2023
All-solid-state lithium-sulfur batteries (ASSLSBs) have high reversible characteristics owing to the high redox potential, high theoretical capacity, high electronic conductivity, and low Li diffusion energy barrier in the cathode. Monte Carlo simulations with cluster expansion, based on the first-principles high-throughput calculations, predicted a phase structure change from LiFeS (3̄1) to FeS (3̄) during the charging process. LiFeS is the most stable phase structure.
View Article and Find Full Text PDF